Publications 2024-2025

  1. Boron-Rich Metallaboranes from κ²-N,E-chelated Ru Complexes (E = S or Se): A Direct Route to Ruthenaboranes: A. Ahmad, U. Gupta, and S. Ghosh, Inorg. Chem., 2025, 64, 18735. [pdf]
  2. Cluster versus Coordination: The Chemistry of Cyclopentadienyl Titanium and Vanadium Complexes with B- and C-functionalized Carborane-thiols, [C2B10H12-n(SH)n] (n = 2 or 3): S. Bairagi, D.K. Patel, D. Chatterjee, M. Kučeráková, J. Macháček, T. Base, T. Pradeep and S. Ghosh, Chem. Sci., 2025, 16, 14127. [pdf] [2025 Chemical Science HOT Article Collection]
  3. Cooperative B-H Bond Activation: A Direct Route to Monometallic Diborane(5) and Dihydroborate Complexes: S. Saha, P. Chakrabortty, and S. Ghosh, Chem. Eur. J., 2025, 31, e02125. [pdf]
  4. Syntheses, Structures, and Theoretical Insights of Homobimetallic Ruthenium Complexes Comprising Mercaptobenzothiazolyl Ligand: A. Ahmad, U. Gupta, S. Jaiswal and S. Ghosh, Organometallics, 2025, 44, 1362. [pdf]
  5. Diborane and Bis(boryl) Complexes of Osmium Stabilized in the Coordination Sphere of [Cp*Os] (Cp* = η5-C5Me5): D. Chatterjee, S. Shyamal and S. Ghosh, Organometallics, 2025, 44, 1075. [pdf]
  6. Heavier Chalcogenate-Bridged Manganese Carbonyl Complexes: Synthesis, Reactivity and Electrochemical Investigation: S. Mishra, T. Dolkar, A. Pareek, R. Maji, A. Dutta and S. Ghosh, Chem. Asian J., 2025, 0, e202401820. [pdf]
  7. Hypoelectronic Titanaboranes: Icosahedral and Tetracapped Tetrahedral Clusters Comprising Bridging Hydrides: S. Bairagi, D. Chatterjee, S. Giri and S. Ghosh, Chem. Commun., 2025, 61, 3696.[pdf] [Featured Structure Friday]
  8. Cooperative B-H Activation: Ligand Diversity in Groups 6 and 8 Transition Metal κ2–N,E-chelated Complexes (E = S or Se): S. Saha, S. Mohapatra, M. Kumar, D. Yadav and S. Ghosh, Inorg. Chem., 2025, 64, 2618. [pdf]
  9. A Pair of Dinuclear Fe(II) Enantiomers: Syntheses and Structures of ΛΔ/ΔΛ-Bis(Dihydridoborate) Complexes: U. Kaur, S. Gayen, H. Sharma, K. Vanka and S. Ghosh, Chem. Eur. J., 2025, 31, e202404469. [pdf]
  10. Recent Advances of B-P Coupling Reactions: Conventional and Efficient Alternative Routes: S. Gayen and S. Ghosh, Eur. J. Inorg. Chem., 2025, 28, e202400732. [pdf]
  11. The Insertion Reactions of GeCl2 with Mono- and Bis-κ2-N,S-Chelated Ru(II) Complexes: A. Ahmad, F. Assanar, U. Gupta, P. Shukla, S. Nagendran and S. Ghosh, Eur. J. Inorg. Chem., 2025, 28, e202400660. [pdf]
  12. Stabilization of Ethane-like Dianionic Diborane(6) in Monometallic Titanium Complexes and its Subsequent B(sp3)-B(sp3) Bond Cleavage: S. Bairagi, S. Giri, G. Joshi, E. D. Jemmis and S. Ghosh, Angew. Chem. Int. Ed., 2025, 64, e202417170. [pdf]
  13. Osmium Borallyl Complexes: Structure and Bonding of [L(PPh3)(H)Os(ηn-B3H5L’2)], (L = H, Cp*; n = 5, 3; L’ = C5H4NS, H)(Cp* = η5-C5Me5): S. Gayen, S. Shyamal, F. Assanar and S. Ghosh, Organometallics, 2024, 43, 2935. [pdf]
  14. Osmaborane Clusters with B4 and B5 Rings Stabilized in the Coordination Sphere of {OsLn} (Ln = η5-C5Me5 or H2(PPh3)2): S. Shyamal, D. Chatterjee, K. Kar and S. Ghosh, Inorg. Chem., 2024, 63, 21838. [pdf]
  15. Small Ring Molecules Comprising 3-6 Boron Atoms: An Account on Synthesis, Structure, and Orbital Engineering: S. Kar, S. Bairagi, G. Joshi, E. D. Jemmis, H. Himmel and S. Ghosh, Acc. Chem. Res., 2024, 57, 2901. [pdf]
  16. Metal-Rich Fused Clusters: Syntheses, Structures and Bonding of Heteronuclear Condensed Metallaboranes: S. Jaiswal, A. N. Pradhan and S. Ghosh, Organometallics, 2024, 43, 2086. [pdf]
  17. Quantifying Variation in Cooperative B-H Bond Activations by Os(II) and Os(III) κ2-N,S-chelated Complexes: Same, but Different: S. Gayen, F. Assanar, S. Shyamal, P. D. Dorairaj and S. Ghosh, Chem. Sci., 2024, 15, 15913. [pdf]
  18. Beyond S and Se: Electrocatalytic Hydrogen Production by Tellurolate-Bridged Co(III)-Mn(I) Heterodinuclear Complexes: S. Mishra, T. Dolkar, A. Pareek, R. Bonthapally, D. Maity, A. Dutta and S. Ghosh, Inorg. Chem., 2024, 63, 16918. [pdf]
  19. Reactivity of [(Cp*CoPh)(Cp*Co)(μ-TePh)(μ–ĸ2-Te,H-TeBH3)] towards [M(CO)5·THF] (M = Mo and W), CS2 and [Fe2(CO)9]: A. N. Pradhan, S. Bairagi and S. Ghosh, Inorg. Chem., 2024, 63, 15648. [pdf]
  20. Polyhedral and Macropolyhedral Metal-Rich Cobaltaboranes: A 25-Vertex Hourglass-Shaped Cluster: S. Giri, C. Nandi, P. Nampi, R. M. Parmar and S. Ghosh, Inorg. Chem., 2024, 63, 11639. [pdf] (Invited article for ACS Special Issue Celebrating the CRSI 25th Anniversary)
  21. Synthesis, Structures and Bonding of Group 6 Thio-complexes: S. Mohapatra, A. Haridas, M. Kumar and S. Ghosh, Inorg. Chim. Acta, 2024, 571, 122205. [pdf] (Invited article for Special issue in honour to Professor Ashutosh Ghosh)
  22. Bimetallic Perthiocarbonate Complexes of Cobalt: Synthesis, Structure and Bonding: A. N. Pradhan, S. Mishra, U. Kaur, B. K. Rout, J.-F. Halet and S. Ghosh, Molecules, 2024, 29, 2688. [pdf] (Invited article for Exclusive Feature Papers in Inorganic Chemistry 2.0)
  23. Borate ligand derived from CS2 unveiling ruthenium dithioformate and trithia-borinane complexes: A. Ahmad, S. Gayen, S. Mishra, Z. Afsan, L. Vendier and S. Ghosh, Polyhedron, 2024, 256, 116986. [pdf] (Invited article for ACCC9 Special Issue)
  24. Syntheses, Structures, and Bonding of Boron Containing Niobium and Ruthenium Clusters Stabilized by Chalcogens: S. Bairagi, D. Chatterjee, A. De, M. Cordier, T. Roisnel and S. Ghosh, J. Organomet. Chem., 2024, 1012, 123126. [pdf] (Invited article for WT Wong Special Issue)
  25. Synthesis, Structure and Bonding of Group 8 Transition Metal Germyl Complexes, [Cp*M {κ2-Ge,S-GeCl2C7H4NS2}(PPh3)] (M = Ru or Os): S. Saha, F. Assanar, A. Ahmad, A. Bains, S. Nagendran and S. Ghosh, Organometallics, 2024, 43, 718. [pdf]
  26. Bridging Bis(boryl) and Borylene Species Stabilized in the Coordination Sphere of Ruthenium Metals: U. Kaur, S. Jaiswal, M. Cordier, B. P. T. Fokwa and S. Ghosh, Organometallics, 2024, 43, 617. [pdf]
  27. Rule Breaker Boron Clusters: A New Class of Hypoelectronic Osmaborane Clusters [(Cp*Os)2BnHn] (n = 6-10): K. Kar, S. Kar and S. Ghosh, Chem. Sci., 2024, 15, 4179. [pdf]
  28. Doubly Base-Stabilised Diborane(4) and Borato-Boronium Species and Their Chemistry with Chalcogens: A. Ahmad, S. Gayen, S. Mishra, Z. Afsan, S. Bontemps and S. Ghosh, Inorg. Chem., 2024, 63, 3376. [pdf]
  29. Hetero-trimetallic Complexes Comprising Bridging Boryl and Borylene Ligands: An Experimental and Theoretical Study: S. Bairagi, S. Giri, D. K. Patel, D. Luong, B. P. T. Fokwa and S. Ghosh, Dalton Trans., 2024, 53, 3191. [pdf]
  30. Metal Rich Metallaboranes: Synthesis, Structure and Bonding of pileo-[(Cp*Ru)2M(CO)3(µ-H)(µ-E)(µ3-BH)B2H5] (M = Mo, W, E = CO, and M = Mn, E = H) Clusters: A. N. Pradhan, S. Jaiswal, M. Cordier, J.-F. Halet and S. Ghosh, Inorganics, 2024, 12, 7. [pdf] (Invited article for a special issue on Boron Chemistry: Fundamentals and Applications)
  31. B-P Coupling: Metal Stabilized Phosphinoborate Complexes: S. Gayen, S. Shyamal, S. Mohapatra, P. K. S. Antharjanam and S. Ghosh, Chem. Eur. J., 2024, 30, e202302362. [pdf] (Invited article for a special issue on Special Collection: p-block elements)
  32. Transition Metal Triple-decker Sandwich Complexes Containing Group 13 Elements: D. Chatterjee, S. Bairagi and S. Ghosh, Chem. Asian J., 2024, 12, e202300864. [pdf]