Publications 2009 – 2011

  1. C – H Activation of Arenes and Heteroarenes by Early Transition Metallaborane, [(Cp*Ta)2B5H11] (Cp* = η5-C5Me5): S. K. Bose, K. Geetharani and S. Ghosh, Chem. Commun., 2011, 47, 11996.[pdf ]
  2. Aqueous organometallic chemistry: Synthesis and characterisation of γ,δ unsaturated alkynyl substituted Fischer-Carbene complexes of group 6 transition metals: R. Ganesamoorthi, A. Thakur and S. Ghosh, Curr. Sci., 2011, 101, 1347.[pdf]
  3. Synthesis and reactivity of dimolybdathiaborane cluster [(Cp*Mo)2B4SH6] (Cp* = η5-C5Me5): K. K. V. Chakrahari and S. Ghosh, J. Chem. Sci., 2011, 123, 847.[pdf] [Invited article for a special issue on the occasion of The International Year of Chemistry]
  4. Synthesis, Characterization, and Electronic Structure of New Type of Heterometallic Boride Clusters: S. K. Bose, K. Geetharani, S. Sahoo, K. H. K. Reddy, B. Varghese, E. D. Jemmis and S. Ghosh, Inorg. Chem., 2011, 50, 9414. [pdf]
  5. A Homometallic Tricapped Cubane Cluster: [(Cp*Mo)4B4H4(µ4-BH)3] (Cp* = η5-C5Me5): A. Thakur, S. Sahoo and S. Ghosh, Inorg. Chem., 2011, 50, 7940.[pdf]
  6. A Novel Eleven Vertex, Eleven-Skeletal Electron Pair Tantalaborane of Unusual Shape: S. K. Bose and S. Ghosh, Organometallics, 2011, 30, 4788.[pdf]
  7. Synthesis and Structural Characterization of an Open Cage Dithiatungstaborane [(CpW)2B4H4S2] Cluster: R. S. Dhayal, S. J. Ponniah, S. Sahoo and S. Ghosh, Ind. J. Chem., 2011, 50A, 1363. [Invited article for a special issue dedicated to A. P. C. Ray on his 150th birth anniversary].[pdf]
  8. Metallaheteroborane Clusters of Group 5 Transition Metals Derived from Dichalcogenide Ligands: S. K. Bose, S. M. Mobin and S. Ghosh, J. Organomet. Chem., 2011, 696, 3121.[pdf]
  9. A Highly Selective Redox, Chromogenic and Fluorescent Chemosensor for Hg2+ in Aqueous Solution Based on Ferrocene-Glycine Bioconjugates: A. Thakur, S. Sardar and S. Ghosh, Inorg. Chem., 2011, 50, 7066. [pdf]
  10. Cluster Expansion Reactions of Group 6 and 8 Metallaboranes Using Transition Metal Carbonyl Compounds of Groups 7-9: K. Geetharani, S. K. Bose, S. Sahoo, B. Varghese, S. M. Mobin and S. Ghosh, Inorg. Chem., 2011, 50, 5824.[pdf]
  11. Synthesis, Structure and Characterization of Dimolybdaheteroboranes: R. S Dhayal, V. Ramkumar and S. Ghosh, Polyhedron, 2011, 30, 2062. [pdf]
  12. High Yield Synthesis of a Hybrid 2,3,4,5-Tetracarba-1,6-nido-hexaborane(6) Cluster with an exo-Polyhedral Boracycle: H. Braunschweig, S. Ghosh, T. Kupfer, K. Radacki and J. Wahler, Chem. Eur. J., 2011, 17, 4081. [pdf]
  13. New molybdaborane clusters with a bridged phosphido ligand: K. K. V. Chakrahari, S. M. Mobin and S. Ghosh, J. Cluster Sci., 2011, 22, 149. [pdf]
  14. A Family of Heterometallic Cubane-Type Clusters with an exo-Fe(CO)3Fragment Anchored to Cubane: K. Geetharani. S. K. Bose, S. Sahoo and S. Ghosh, Angew. Chem. Int. Ed., 2011, 50, 3908.[pdf]
  15. Condensed Tantalaborane Clusters: Synthesis and Structures of [(Cp*Ta)2B5H7{Fe(CO)3}2] and [(Cp*Ta)2B5H9{Fe(CO)3}4]: S. K. Bose, K. Geetharani, B. Varghese and S. Ghosh, Inorg. Chem., 2011, 50, 2445.[pdf]
  16. Synthesis and Characterization of Binuclear µ-Oxo and µ-Telluro Molybdenum(V) Complexes, [Cp*Mo(O)(µ-Te)]2: K. K. V. Chakrahari, R. S. Dhayal and S. Ghosh, Polyhedron, 2011, 30, 1048.[pdf]
  17. A New Entry into Ferraborane Chemistry: Synthesis and Characterization of Heteroferraborane Complexes: K. Geetharani, S. K. Bose, D. Basak, M. V. Suresh and S. Ghosh, Inorg. Chim. Acta, 2011, 372, 42.[pdf] (Invited article)
  18. Synthesis and Structure of [Cp*Ru(CO)2(μ-H){RuFe3(CO)9}]: An Unusual Mixed-Metal Tetrahedral Cluster with an Exopolyhedral Metal Fragment: K. Geetharani, S. K. Bose and S. Ghosh, Organometallics, 2011, 30, 191.[pdf]
  19. Ring Expansion of a Cp Moiety Upon CO Insertion: Synthesis and Characterization of [(n6-C6H5OCo)Co3(CO)9]: S. K. Bose, K. Geetharani and S. Ghosh, J. Organomet. Chem., 2010, 695, 2567.[pdf]
  20. Chemistry of Molybdaboranes: Synthesis, Structures and Characterization of a New Class of Open-Cage Dimolybdaheteroborane Clusters: R. S. Dhayal, K. K. V. Chakrahari, B. Varghese, S. M. Mobin and S. Ghosh, Inorg. Chem., 2010, 49, 7741.[pdf]
  21. From Metallaborane to Borylene Complexes:  Syntheses and Structures of Triply Bridged Ruthenium and Tantalum Borylene Complexes:  K. Geetharani, S. K. Bose, B. Varghese and S. Ghosh, Chem. Eur. J., 2010, 16, 11357.[pdf]
  22. Unusual Organic Chemistry of a Metallaborane Substrate: Formation of Tantalaborane Complex with Bridging Acyl Group ( m,h2): S. K. Bose, K. Geetharani, B. Varghese and S. Ghosh. Inorg. Chem., 2010, 49, 6375.[pdf]
  23. Chemistry of Vanadaboranes: Synthesis, Structures and Characterization of Organ vanadium Sulfide Clusters with Disulfido linkage: S. K. Bose, K. Geetharani, V. Ramkumar, B. Varghese and S. Ghosh, Inorg. Chem., 2010, 49, 2881.[pdf]
  24. Vertex-Fused Metallaborane Clusters: Synthesis, Characterization and Electronic Structure of [(n5-C5Me5Mo)3MoB9H18]: R. S. Dhayal, S. Sahoo, K. H. K. Reddy, S. M. Mobin, E. D. Jemmis and S. Ghosh, Inorg. Chem., 2010, 49, 900.[pdf]
  25. Direct Insertion of Sulphur, Selenium and Tellurium atoms into Metallaborane Cages using Chalcogen Powders: S. Sahoo, S. M. Mobin and S. Ghosh, J. Organomet. Chem., 2010, 695, 945.[pdf]
  26. Synthesis of Mono and Doubly Alkynyl-Substituted Ferrocene and Its Crystal Engineering Using C-H…O Supramolecular Synthon: A. Thakur, N. N. Adarsh, A. Chakraborty, M. Devi and S. Ghosh, J. Organomet. Chem. 2010, 695, 1059.[pdf]
  27. Fine-Tuning of Metallaborane Geometries:  Chemistry of Metallaboranes of Early Transition Metals Derived from Metal Halides and Monoborane Reagents: S. K. Bose, K. Geetharani, V. Ramkumar, S. M. Mobin and S. Ghosh. Chem. Eur. J., 2009, 15, 13483.[pdf]
  28. A new synthetic route to Lindqvist type clusters [(n-Bu4N)x][M′M5O19] [when x = 2, M′= M = Mo or W; x = 3, M′= Mo, M = W] from metal carbonyl precursors [(CO)5ML] [M = Mo, W; L= CO, C(OMe)(Me)]: A. Thakur, A. Chakraborty, V. Ramkumar and S. Ghosh, Dalton Trans., 2009, 7552.[pdf]
  29. Chlorinated Hypoelectronic Dimetallaborane Clusters: Synthesis,  Characterization and Electronic Structures of (η5-C5Me5W)2B5HnClm (n = 7, m = 2 and n = 8, m = 1): S. Sahoo, K. H. K. Reddy, R. S. Dhayal, S. M. Mobin, V. Ramkumar, E. D. Jemmis and S. Ghosh. Inorg. Chem., 2009, 48, 6509.[pdf]
  30. B-Alkylation and Arylation of (η5-C5Me5Mo)2B5H9: Synthesis and Characterization of Isomeric (η5-C5Me5Mo)2B5H9-nRn (When R = n-Bu, n = 2, 1; R = Ph, n = 2, 1): R. S. Dhayal, K. K. V. Chakrahari, V. Ramkumar and S. Ghosh. J. Cluster Sci., 2009, 20, 565.[pdf]
  31. Borylene-based Direct Functionalization of Organic Substrates: Synthesis, Characterization and Photophysical Properties of σ-Conjugated Borirenes: H. Braunschweig, T. Herbst, D. Rais, S. Ghosh, T. Kupfer, K. Radacki, A. Crawford, R. Ward, T. Marder, I. Fernández and G. Frenking. J. Am. Chem. Soc., 2009, 131, 8989.[pdf]
  32. An Efficient Route to Group 6 and 8 Metallaborane Compounds: Synthesis of arachno-[Cp*Fe(CO)B3H8] and closo-[(Cp*M)2B5H9] (M = Mo, W): K. Geetharani, S. K. Bose, G. Pramanik, T. K. Saha, V. Ramkumar and S. Ghosh. Eur. J. Inorg. Chem. 2009, 1483.[pdf]
  33. Unusual Open Eight-Vertex Oxamolybdaboranes: Structural Characterizations of (η5-C5Me5Mo)2B5(m3-OEt)H6R (R = H and n-BuO): S. Sahoo, R. S. Dhayal, B. Varghese and S. Ghosh. Organometallics, 2009, 28, 1586. [pdf]
  34. Substitution at Boron in Molybdaborane Frameworks: Synthesis and Characterization of Isomeric (η5-C5Me5Mo)2B5HnXm (when X = Cl: n = 5, 7, 8; m = 4, 2, 1 and X = Me: n = 6, 7; m = 3, 2) R. S. Dhayal, S. Sahoo, V. Ramkumar and S. Ghosh, J. Organomet. Chem., 2009, 694, 237.[pdf]
  35. Detachment of tobacco-smoke-material carriers from surfaces by turbulent air flow. H. Ibrahi, S. Ghosh and P. F. Dunn, J. Environ. Monit., 2009, 11, 56.[pdf]