Publications 2021-2023

  1. Degradation chemistry of dimetallaboranes, [(Cp*M)2B5H9+x] with [(Ph2Se2], (x = 2 or 0, M = V or Cr): A. Haridas, D. Chatterjee, S. Giri, A. De and S. Ghosh, Organometallics, 2023, 42, 3199. [pdf]
  2. 16-vertex oblato–hypho-Titanaborane [(Cp*Ti)2B14H18]: S. Kar, S. Bairagi, J.-F. Halet and S. Ghosh, Chem. Commun., 2023, 59, 11676. [pdf]
  3. Diborane and Triborane Species in the Coordination Sphere of Group-8 Transition Metals: A. N. Pradhan, S. Bairagi and S. Ghosh, Inorg. Chem., 2023, 62, 14790. [pdf]
  4. Macropolyhedral syn-B18H22, the “Forgotten” Isomer: D. Patel, B. S. Sooraj, K. Kirakci, J. Machacek, M. Kučeráková, J. Bould, M. Dusek, M. Frey, C. Neumann, S. Ghosh, A. Turchanin, T. Pradeep and T. Base, J. Am. Chem. Soc., 2023, 145, 17975. [pdf]
  5. Base Stabilized σ-Borane Complex of Group 5 Metals: Synthesis and Structure of [(η5-C5Me5)Ta(H3BNC5H4)(C5H4NS)(η2-S2)]: A. Haridas, S. Saha, S. Bedajna and S. Ghosh, Eur. J. Inorg. Chem., 2023, 26, e202300312. [pdf]
  6. Metal-Rich Metallaboranes: Synthesis, Structure, and Bonding of Heteronuclear Trimetallic Clusters containing (µ3-BH) Ligand: A. N. Pradhan, S. Jaiswal and S. Ghosh, Eur. J. Inorg. Chem., 2023, 26, e202300254. [pdf]
  7. Synthesis, Structure and Bonding of the Tungstaboranes [Cp*W(CO)2B3H8] and [(Cp*W)3(CO)2B4H7]: S. Mohapatra, S. Gayen, S. Shyamal, J.-F. Halet and S. Ghosh, Inorganics, 2023, 11, 248. [pdf] (Invited article for a special issue on Fifth Element: The Current State of Boron Chemistry)
  8. Synthesis and Structures of Ruthena-octahydrotetraborane Complexes: A. Ahmad, S. Saha, M. Zafar, M. Cordier and S. Ghosh, Eur. J. Inorg. Chem., 2023, 26, e202300196. [pdf]
  9. Combined B-H and Si-H bond activations at ruthenium: R. Ayyappan, K. Saha, U. Kaur, S. Gayen, L. Vendier, S. Sabo-Etienne, S. Ghosh and S. Bontemps, Organometallics, 2023, 42, 752. [pdf]
  10. Syntheses, Structures, and Electronic Properties of Mono- and Bimetallic Thiolato Complexes Containing Unusual Coordination Modes of Thiolato Ligands: S. Bairagi, A. N. Pradhan, M. Cordier, T. Roisnel and S. Ghosh, Eur. J. Inorg. Chem., 2023, 26, e202300060. [pdf]
  11. Triple-decker complexes comprising heterocyclic middle-deck with coinage metals: C. Nandi, R. Bag, S. Giri, A. Roy, M. Cordier and S. Ghosh, J. Organomet. Chem., 2023, 990, 122667. [pdf]
  12. Synthesis and chemistry of Ru-bimetallic homocubane clusters: U. Kaur, S. Jaiswal, S. Gayen and S. Ghosh, J. Organomet. Chem., 2023, 989, 122642. [pdf] (Invited article for a special issue on ICOMC22)
  13. Chemistry of CS2 and CS3 Bridged Decaborane Analogues: Regular Co-ordination versus Cluster Expansion: K. Kar, S. Saha, R. M. Parmar, A. Roy, M. Cordier, T. Roisnel and S. Ghosh, Molecules, 2023, 28, 998. [pdf] (Invited article for a special issue on New Boron Chemistry: Current Advances and Future Prospects)
  14. Synthesis and Structures of Facial and Meridional Stereoisomers of κ2-N,S-Chelated Ruthenium Borate Complexes: A. Ahmad, S. Saha, M. Zafar, T. Roisnel, P. Ghosh and S. Ghosh, Eur. J. Org. Chem, 2023, 989, e202201283. [pdf] (Invited article for a special issue on Boron Chemistry)
  15. Carborane-thiol protected copper nanoclusters: Stimuli-responsive materials with tunable phosphorescence: A. Jana, M. Jash, W. Ahmed Dar, J. Roy, P. Chakraborty, G. Paramasivam, S. Lebedkin, K. Kirakci, S. Manna, S. Antharjanam, J. Machacek, M. Kucerakova, S. Ghosh, K. Lang, M. M. Kappes, T. Base and T. Pradeep, Chem. Sci., 2023, 14, 1613. [pdf]
  16. Synthesis and Chemistry of Dihydridoborate Group 7 Metal Complexes with Varied N,E-Chelated Ligands (E = O, NH or S): K. Pathak, S. Mishra, C. Nandi, S. Saha, and S. Ghosh, Inorg. Chem., 2023, 62, 160. [pdf]
  17. Thiolate Bridged Hetero-Dinuclear Manganese-Cobalt Complexes with Bridging Hydride Ligands: K. Pathak, S. Mishra, S. Bairagi, B. Rajeshwaree, A. Dutta and S. Ghosh, Organometallics, 2023, 42, 133. [pdf] [Front Cover]
  18. Transition Metal Borate Complexes Containing κ0-κ6 Denticity of Scorpionate Borate Ligands: S. Saha, F. Assanar and S. Ghosh, Eur. J. Inorg. Chem., 2023, 26, e202200587. [pdf]
  19. Structures and Bonding of Early Transition Metallaborane Clusters: S. Mohapatra, S. Gayen, R. Bag, A. Das, R. Ramalakshmi, M. Cordier and S. Ghosh, Organometallics, 2023, 42, 1077. [pdf] (Invited article for a special issue in “Early Transition Metals in Organometallic Chemistry”)
  20. Trimetallic Chalcogenide Species: Synthesis, Structures, and Bonding: S. Kar, D. Chatterjee, J. -F. Halet and S. Ghosh, Molecules, 2022, 27, 7473. [pdf] (Invited article for Organometallic Chemistry section)
  21. Cluster Growth Reactions: Structures and Bonding of Metal-Rich Metallaheteroboranes Containing Heavier Chalcogen Elements: C. Nandi, A. Roy, K. Kar, M. Cordier and S. Ghosh, Inorg. Chem., 2022, 42, 16750. [pdf]
  22. C. Nandi, K. Kar, A. Roy and S. Ghosh, Metallaboranes and metallaheteroboranes: An overview of single-cage and condensed polyhedral clusters. in: Advances in Inorganic Chemistry. Ed. R. V. Eldik and D. Chatterjee, Elsevier, 2022.[pdf]
  23. The chemistry of κ2-N,S-chelated Ru(II) complexes with 1,4-diethynylbenzene: Z. Afsan, A. Ahmad, M. Zafar, A. Das, T. Roisnel and S. Ghosh, Polyhedron, 2022, 116120. [pdf] (Invited article for a special issue for ACCC8)
  24. Hexagonal Planar [B6H6] within a [B6H12] Borate complex; Structure and Bonding of [(Cp*Ti)2(μ–ɳ6:ɳ6-B6H6)(μ-H)6]: S. Kar, S. Bairagi, A. Haridas, G. Joshi, E. D. Jemmis and S. Ghosh, Angew. Chem. Int. Ed., 2022, 61, e202208293. [pdf] [Highlighted in ChemistryViews]
  25. Cooperative B-H bond activation: Dual sites borane activation by redox active κ2-N,S-chelated complexes: M. Zafar, A. Ahmad, S. Saha, R. Rongala, T. Roisnel and S. Ghosh, Chem. Sci., 2022, 13, 8567. [pdf]
  26. K. Pathak, S. Mishra and S. Ghosh, Boron: Polyhedral Metallaboranes. in: Encyclopedia of Inorganic and Bioinorganic Chemistry. Ed. B. Sarkar, Wiley, 2022. [pdf]
  27. Metal-rich clusters: synthesis, structure and bonding of metallaboranes featuring µ5-boride and triply bridging borylene units: A. N. Pradhan, B. K. Rout, Prof. J.-F. Halet and S. Ghosh, Inorg. Chim. Acta, 2022, 540, 121045. [pdf] (Invited article for a special issue dedicated to Professor R. Bruce King)
  28. Vertex-Fused Clusters Featuring a Flattened Butterfly: S. Kar, K. Kar and S. Ghosh, Organometallics, 2022. 41, 1125. [pdf]
  29. Coordination and Hydroboration of Ru(II)-Borate Complexes: Dihydridoborate vs. Bis(dihydridoborate): K. Pathak, S. Gayen, S. Saha, C. Nandi, S. Mishra and S. Ghosh, Chem. Eur. J., 2022, 28, e202104393. [pdf]
  30. Cooperative B-H activation by Cp* based κ2-N,S-chelated Ru(II) and Mo(II) complexes (Cp* = ƞ5-C5Me5): S. Saha, A. Haridas, F. Assanar, C. Bansal, P. K. S. Antharjanam and S. Ghosh, Dalton Trans., 2022, 51, 4806. [pdf]
  31. R. Bag, S. Bairagi, B. K. Rout and S. Ghosh, Transition Metal Diborane and Diborene Complexes: an Overview. in: Encyclopedia of Inorganic and Bioinorganic Chemistry. Ed. R. Melen, Wiley, 2022. [pdf]
  32. S. Kar, A. N. Pradhan and S. Ghosh, Polyhedral Metallaboranes and Metallacarboranes. in: Comprehensive Organometallic Chemistry IV. Ed. G. Parkin, K. Meyer, D. O’hare, Elsevier, 2022, 9, 263-369. [pdf]
  33. Hydroboration reactions using transition metal borane and borate complexes: An overview (frontier article): K. Saha and S. Ghosh, Dalton Trans., 2022, 51, 2631.[pdf]
  34. Substitution at B-H vertices of group 5 metallaborane clusters: A. Haridas, S. Bedajna and S. Ghosh, J. Organomet. Chem., 2022, 961, 122250. [pdf]
  35. K. Pathak, K. Saha and S. Ghosh, Nanovehicles and boron clusters. in: Fundamentals and Applications of Boron Chemistry. Ed. Y. Zhu and N. S. Hosmane, Elsevier, 2022, 2, 291. [pdf]
  36. Chalcogen Stabilized Borate Complexes of Tantalum: S. Kar, K. Kar, S. Bairagi, M. Bhattacharyya, M. G. Chowdhury, and S. Ghosh, Inorg. Chimica. Acta., 2022, 530, 120685. [pdf]
  37. Metallaheteroboranes with group 16 elements: Aspects of synthesis, framework and reactivity: K. Pathak, C. Nandi and S. Ghosh Coord. Chem. Rev., 2022, 453, 214303. [pdf]
  38. Light-Activated Intercluster Conversion of an Atomically Precise Silver Nanocluster: A. Jana, M. Jash, A. Kumar Poonia, G. Paramasivam, M. R. Islam, P. Chakraborty, S. Antharjanam, J. Machacek, S. Ghosh, K. N. V. D. Adarsh, T. Base, and T. Pradeep ACS Nano, 2021, 15, 15781. [pdf]
  39. Metal Coordinated Tri- and Tetraborane Analogues: S. Kar, S. Bairagi, K. Kar, T. Roisnel, V. Dorcet, and S. Ghosh Eur. J. Inorg. Chem., 2021, 4443. [pdf] [Cover Page]
  40. Metal stabilized [B8H8]2- derivatives with dodecahedral structure in solid- and solution-state: [(Cp2MBH3)2B8H6], (Cp = ƞ5-C5H5; M = Zr (1-Zr) and Hf (1-Hf)): S. Kar, S. Bairagi, G. Joshi, E. D. Jemmis and S. Ghosh Chem. Eur. J., 2021, 27, 15637. [pdf]
  41. Impact of the alkali metal on the structural and dynamic properties of the anionic pentahydride ruthenium complexes [M(THF)x][RuH5(PCy3)2] (M = Li, Na, K): R. Ayyappan, K. Saha, M. Grellier, E. Clot, L. Vendier, S. Ghosh, S. Sabo-Etienne and S. Bontemps Organometallics, 2021, 40, 3024. [pdf]
  42. Planar triple-decker and capped octahedral clusters of group-6 transition metals: R. Bag, S. Gayen, S. Mohapatra, P. K. S. Antharjanam, J.-F. Halet and S. Ghosh J. Organomet. Chem., 2021, 952, 122023. [pdf] (Invited article for a special issue on the occasion of Prof. Pradeep Mathur 65th birthday)
  43. Stabilization of dichalcogenide ligands in the coordination sphere of ruthenium system: K. Saha, S. Gayen, U. Kaur, T. Roisnel and S. Ghosh Dalton Trans., 2021, 50, 12990. [pdf]
  44. Directed Synthesis of CS2 and CS3-Bridged Decaborane-14 Analogues: C. Nandi, K. Kar, S. Gayen, T. Roisnel, and S. Ghosh Inorg. Chem., 2021, 60, 12367. [pdf]
  45. Contemporary developments in transition metal boryl complexes: An overview: U. Kaur, K. Saha, S. Gayen and S. Ghosh Coord. Chem. Rev., 2021, 446, 214106. [pdf]
  46. Structural and electronic analysis of bimetallic thiolate complexes of group-5 transition metal ions: U. Kaur, K. Saha, S. Bairagi, A. Das, T. Roisnel, T. K. Paine and S. Ghosh J. Organomet. Chem., 2021, 949, 121943. [pdf] (Invited article for a special issue on the occasion of Prof. Pradeep Mathur 65th birthday)
  47. Metal-rich Metallaboranes: Synthesis, Structures and Bonding of Bi- and Trimetallic Open-Faced Cobaltaboranes: K. Pathak, C. Nandi, J.-F. Halet, and S. Ghosh Inorganics, 2021, 9, 28. [pdf]
  48. S. Kar and S. Ghosh, Borane Polyhedra beyond Icosahedron. in: Structure and Bonding. Ed. D. M. P. Mingos, Springer, Berlin, Heidelberg, 2021, 187, 109-138. [pdf]
  49. Triple-Decker Sandwich Complexes of Tungsten with Planar and Puckered Middle-Deck: R. Bag, R. Prakash, S. Saha, T. Roisnel, and S. Ghosh Inorg. Chem., 2021, 60, 3524. [pdf]
  50. Chemistry of group 5 metallaboranes with heterocyclic thiol ligands: a combined experimental and theoretical study: R. Prakash, A. Haridas, K. Bakthavachalam, T. Roisnel, J. -F. Halet and S. Ghosh Dalton Trans., 2021, 50, 4036. [pdf]
  51. Recent Advances in the Synthesis and Reactivity of Transition Metal σ-Borane/-Borate Complexes: K. Saha, D. K. Roy, R. D. Dewhurst, S. Ghosh and H. Braunschweig Acc. Chem. Res., 2021, 54, 1260. [pdf]
  52. Synthesis, Structures and Bonding of Metal-rich Metallaboranes Comprising Triply Bridging Borylene and Boride Moieties: S. Gomosta, S. Kar, A. N. Pradhan, S. Bairagi, V. Ramkumar and S. Ghosh Organometallics, 2021, 40, 529. [pdf]
  53. Synthesis and characterization of group 6-9 metal-rich homo- and hetero-metallaboranes: R. Bag, S. Gomosta, A. N. Pradhan, T. Roisnel and S. Ghosh J. Indian Chem. Soc., 2021, 98, 100040. [pdf]
  54. Metal-rich Metallaboranes: Clusters Containing Triply and Tetra Bridging Borylene and Boride Units: S. Kar, A. N. Pradhan and S. Ghosh Coord. Chem. Rev., 2021, 436, 213796. [pdf]
  55. Cooperative B-H and Si-H Bond Activations by κ2-N,S-chelated Ruthenium Borate Complexes: Md. Zafar, R. Ramalakshmi, A. Ahmad, P. K. S. Antharjanam, S. Bontemps, S. Sabo-Etienne and S. Ghosh Inorg. Chem., 2021, 60, 1183. [pdf]
  56. Synthesis and reactivity of phosphine borohydride compounds: R. Ayyappan, Y. Coppel, L. Vendier, S. Ghosh, S. Sabo- Etienne and S. Bontemps Chem. Commun., 2021, 57, 375. [pdf]