{"id":967,"date":"2020-11-18T05:26:54","date_gmt":"2020-11-18T05:26:54","guid":{"rendered":"http:\/\/m2square.net\/ghosh\/?page_id=967"},"modified":"2022-10-05T10:26:04","modified_gmt":"2022-10-05T10:26:04","slug":"publications-1997-2002","status":"publish","type":"page","link":"https:\/\/chem.iitm.ac.in\/Faculty\/ghosh\/?page_id=967","title":{"rendered":"Publications 1997 – 2002"},"content":{"rendered":"
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  1. The reaction of Cp*ReH6<\/sub>, Cp* = C5<\/sub>Me5<\/sub> with monoborane to yield a novel rhenaborane. Synthesis and characterization of arachno<\/em>-Cp*ReH3<\/sub>B3<\/sub>H8<\/sub>: S. Ghosh, A. M. Beatty, T.P. Fehlner. Collect. Czech. Chem. Commun.<\/em>,\u00a02002<\/strong>, 67<\/em>, 808.[pdf<\/a>]\u00a0<\/li>\n
  2. Synthesis and Characterization of Bicapped Hexagonal Bipyramidal 2,3-Cl2<\/sub>-1,8-{Cp*Re}2<\/sub>B6<\/sub>H4<\/sub> [{Cp*Re}2<\/sub>{\u00b5 n6<\/sup>-n6<\/sup>-1,2-B6<\/sub>H4<\/sub>Cl2<\/sub>}, Cp* = n5<\/sup>-C5<\/sub>Me5<\/sub>]: The Missing Link Connecting (p – 2) Skeletal Electron Pair Hypoelectronic Rhenaboranes and 24-Valence Electron Triple-Decker Complexes: S. Ghosh, A. M. Beatty and T. P. Fehlner. J. Am. Chem. Soc.<\/em>,\u00a02001<\/strong>, 123<\/em>, 9188.[pdf<\/a>]<\/li>\n
  3. Synthesis of (Cp*Re)2<\/sub>Bn<\/sub>Hn<\/sub>, n = 8-10, Cp* = n5<\/sup>-C5<\/sub>Me5<\/sub>. Metal Boride Particles that Stretch the Cluster Structure Paradigms: S. Ghosh, M. Shang, Y. Li and T. P. Fehlner, Angew. Chem. Int. Ed.<\/em>,\u00a02001<\/strong>, 40<\/em>, 1125.[pdf<\/a>] (HIGHLIGHT appeared in Angew.Chem. 2002, 41, 1976 ; Chemmie 2002, 21, 98 and C & EN News<\/em>)<\/li>\n
  4. Metallaboranes of the earlier transition metals. An arachno<\/em> nine-vertex, nine-skeletal electron pair rhenaborane of novel shape: importance of total vertex connectivities in such system: S. Ghosh, A. L. Rheingold, T. P. Fehlner, Chem. Commun.<\/em>, 2001<\/strong>, 895.[pdf<\/a>]\u00a0<\/li>\n
  5. Role of Transition Metal in Metallaborane Chemistry. Comparison of the Reactivity of (Cp*Cr)2<\/sub>B4<\/sub>H8<\/sub> and (Cp*ReH2<\/sub>)2<\/sub>B4<\/sub>H4<\/sub> with Small Molecules and Metal Fragments: S. Ghosh, X. Lei, M. Shang and T. P. Fehlner, Inorg. Chem.,<\/em>\u00a02000<\/strong>, 39<\/em>, 5373.[pdf<\/a>]\u00a0<\/li>\n
  6. Symmetrical Scission of the Coordinated Tetraborane in (Cp*ReH2<\/sub>)B4<\/sub>H4<\/sub> on CO Addition and Reassociation of the Coordinated Diboranes on H2<\/sub> loss: S. Ghosh, X. Lei, C. L. Cahill and T. P. Fehlner. Angew. Chem. Int. Ed.<\/em>,\u00a02000<\/strong>, 39<\/em>, 2900.[pdf<\/a>]\u00a0<\/li>\n
  7. Comparison of the Geometric and Molecular Orbital Structures of (Cp*Cr)2<\/sub>B4<\/sub>H8<\/sub> and (Cp*Re)2<\/sub>B4<\/sub>H8<\/sub>, Cp* =n5<\/sup>-C5<\/sub>Me5<\/sub>. Structural Consequences of Delocalized Electronic Unsaturation in a Metallaborane Cluster: S. Ghosh, M. Shang and T. P. Fehlner, J. Organomet. Chem.<\/em>,\u00a02000<\/strong>, 614<\/em>, 92.[pdf<\/a>]<\/li>\n
  8. Annulation with and without CO insertion: Striking a Balance in Reactivity of Chromium Carbene Complexes with Chalcogen-Stabilized Iron Cluster Appendage: P. Mathur, S. Ghosh, A. Sarkar, A. L. Rheingold and I. A. Guzei, Tetrahedron<\/em>, 2000<\/strong>, 56<\/em>, 4995.[pdf<\/a>]\u00a0<\/li>\n
  9. Non-linear Optical Properties of the Mixed-Metal Mixed-Chalcogen Clusters [Fe2<\/sub>(CO)6<\/sub>{\u00b5 -SeC(Ph)=C(Se)}{(OEt<\/sub>)C=Cr(CO)5<\/sub>] and [Fe2<\/sub>(CO)6<\/sub>Se2<\/sub>{\u00b5 -(CO)3<\/sub>Cr( n5<\/sup>-C5<\/sub>H)(CH2<\/sub>Ph)(Ph)(OEt<\/sub>)}: P. Reji, G. K. Ravindra, P. Mathur and S. Ghosh, Chem. Phys. Lett.<\/em>,\u00a01999<\/strong>, 313<\/em>, 719.[pdf<\/a>]<\/li>\n
  10. A Novel Coordinated Inorganic Benzene. The synthesis and Characterization of {n5<\/sup>-C5<\/sub>Me5<\/sub>Re}2<\/sub>{\u00b5-n6<\/sup>:n6<\/sup>-B4<\/sub>H4<\/sub>Co2<\/sub>(CO)5<\/sub>}. S. Ghosh, M. Shang and T. P. Fehlner, J. Am. Chem. Soc.<\/em>,\u00a01999<\/strong>, 121<\/em>, 7451. [pdf<\/a>] (Highlight in Chemistry & Industry, <\/em>1999, 717<\/em>)<\/li>\n
  11. Formation of Vinyl Ether Derivatives in the Reaction of Tributyltin Hydride with Cluster Supported Fischer Carbene Complexes; Structural Characterization of [(CO)6<\/sub>Fe2<\/sub>Te2<\/sub>{\u00b5-PhC=CC(OEt<\/sub>)}W(CO)5<\/sub>]: S. Ghosh, P. Mathur, S. B. Umbarkar, M. G. Walawalkar and V. G. Puranik, J. Organomet. Chem.<\/em>, 1999<\/strong>, 578<\/em>, 150.[pdf<\/a>]\u00a0<\/li>\n
  12. Annulation Reactions of Fischer Carbene Complexes Tethered on a Chalcogen- Stabilized Iron Carbonyl Cluster: Dependence of Reaction Pathway on Chalcogen Atom: S. Ghosh, P. Mathur, A. Sarkar and C. Thoene, Organometallics<\/em>,\u00a01998<\/strong>, 17<\/em>, 3926.[pdf<\/a>]\u00a0<\/li>\n
  13. Isolation and Characterization of [Fe2<\/sub>(CO)6<\/sub>Se2<\/sub>(\u00b5-CO)3<\/sub>Cr(n5<\/sup>-C5<\/sub>H5<\/sub>)(CH2<\/sub>Ph)Ph)(OEt)}], [(CO)6<\/sub>Fe2<\/sub>{\u00b5-EC(Ph)=C(E’) C(H)(OEt)}]2<\/sub> and [(CO)6<\/sub>Fe2<\/sub>{\u00b5 -SC(H)(Ph)C (Te)=C(H)(OEt)}] from the Thermolysis of Fischer Carbene Adducts [(CO)6<\/sub>Fe2<\/sub>EE'{\u00b5-C(Ph)=C-C(OEt)=Cr(CO)5<\/sub>}] (E, E’ = Se and E = S, E’ = Te): S. Ghosh, P. Mathur, A. Sarkar, A. L. Rheingold and I. A. Guzei, J. Organomet. Chem.<\/em>, 1998<\/strong>, 566<\/em>, 159.[pdf<\/a>]<\/li>\n
  14. An Unusual Cyclopentannulation Reaction: Thermolysis of an-Unsaturated Fischer Carbene Complex Anchored on a Fe2<\/sub>(CO)6<\/sub>(\u00b5-Se)2<\/sub> Core: S. Ghosh, P. Mathur, A. Sarkar, A. L. Rheingold and I. A. Guzei, Organometallics<\/em>, 1998<\/strong>, 17<\/em>, 770.[pdf<\/a>]<\/li>\n
  15. Unusual Formation of Vinyl Ether Derivatives in the Reaction of Tributyltin Hydride with Fischer Carbene Complexes Anchored on a Chalcogen-Stabilized Iron Carbonyl: S. Ghosh, P. Mathur, A. Sarkar, C. V. V. Satyanarayana, J. E. Drake and J. Yang, Organometallics<\/em>, 1997<\/strong>, 16<\/em>, 6028.[pdf<\/a>]<\/li>\n
  16. Chemical Modification of the Metal-Carbene Appendage in New, Trimetallic Adducts of Fe2<\/sub>(CO)6<\/sub>(\u00b5-EE’) (E = S, Se and E’ = Se, Te) and Alkynyl Fischer Carbene Complexes (CO)5<\/sub>M=C(OEt)(C CPh) (M = Cr, W). P. Mathur, S. Ghosh, A. Sarkar, C. V. V. Satyanarayana and V. G. Puranik, Organometallics<\/em>, 1997<\/strong>, 16<\/em>, 4392.[pdf<\/a>]\u00a0<\/li>\n
  17. Regioselective Addition of Mixed-Chalcogenide Iron Carbonyl Clusters Fe2<\/sub>(CO)6<\/sub>(\u00b5 -EE’) (E # E’, E, E’ = S, Se, Te) to a Carbon-Carbon Triple Bond Activated by a Metal Carbene Fragment. Structural Characterization of New Trimetallic Adducts Fe2<\/sub>(CO)6<\/sub>{\u00b5-SC(Ph)C(Te)[(OEt)CCr(CO)5<\/sub>]}, Fe2<\/sub>(CO)6<\/sub>{\u00b5SC(Ph)C(Se(OEt)CW(CO)5<\/sub>],and Fe2<\/sub>(CO)6<\/sub>{\u00b5 -SeC(Ph)C(Te) [(OEt)CW(CO)5<\/sub>]}. S. Ghosh, P. Mathur, A. Sarkar, C. V. V. Satyanarayana and V. G. Puranik, Organometallics<\/em>, 1997<\/strong>, 16<\/em>, 3536.[pdf<\/a>]<\/li>\n
  18. Synthesis and spectroscopic characterization of closo<\/em>-Ru4<\/sub>(CO)12<\/sub>(\u00b54<\/sub>,n2<\/sup>-HC2<\/sub>Ph) and closo-Ru4<\/sub>(CO)9<\/sub>(\u00b5-CO)2<\/sub>(\u00b54<\/sub>,n2<\/sup>-HC2<\/sub>Ph)(\u00b54<\/sub>-Se). Crystal structure of closo<\/em> Ru4<\/sub>(CO)12<\/sub>(\u00b54<\/sub>,n2<\/sup>-HC2<\/sub>Ph). S. Ghosh, P. Mathur, M. M. Hossain, C. V. V. Satyanarayana, A. L Rheingold and G. P. A. Yap, J. Organomet. Chem.<\/em>, 1997<\/strong>, 538<\/em>, 57.[pdf<\/a>]<\/li>\n<\/ol>\n<\/div><\/div><\/div><\/div><\/div>","protected":false},"excerpt":{"rendered":"","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"_links":{"self":[{"href":"https:\/\/chem.iitm.ac.in\/Faculty\/ghosh\/index.php?rest_route=\/wp\/v2\/pages\/967"}],"collection":[{"href":"https:\/\/chem.iitm.ac.in\/Faculty\/ghosh\/index.php?rest_route=\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/chem.iitm.ac.in\/Faculty\/ghosh\/index.php?rest_route=\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/chem.iitm.ac.in\/Faculty\/ghosh\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/chem.iitm.ac.in\/Faculty\/ghosh\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=967"}],"version-history":[{"count":37,"href":"https:\/\/chem.iitm.ac.in\/Faculty\/ghosh\/index.php?rest_route=\/wp\/v2\/pages\/967\/revisions"}],"predecessor-version":[{"id":2116,"href":"https:\/\/chem.iitm.ac.in\/Faculty\/ghosh\/index.php?rest_route=\/wp\/v2\/pages\/967\/revisions\/2116"}],"wp:attachment":[{"href":"https:\/\/chem.iitm.ac.in\/Faculty\/ghosh\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=967"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}