{"id":1462,"date":"2021-01-08T09:29:11","date_gmt":"2021-01-08T09:29:11","guid":{"rendered":"http:\/\/chem.iitm.ac.in\/Faculty\/ghosh\/?page_id=1462"},"modified":"2026-02-17T11:13:28","modified_gmt":"2026-02-17T11:13:28","slug":"publications-2025","status":"publish","type":"page","link":"https:\/\/chem.iitm.ac.in\/Faculty\/ghosh\/?page_id=1462","title":{"rendered":"Publications 2024-2025"},"content":{"rendered":"
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  1. Boron-Rich Metallaboranes from \u03ba\u00b2-N,E-chelated Ru Complexes (E = S or Se): A Direct Route to Ruthenaboranes: A. Ahmad, U. Gupta, and S. Ghosh, Inorg. Chem.<\/em>, 2025<\/strong>, 64<\/em>, 18735. [pdf<\/a>]<\/li>\n
  2. Cluster versus Coordination: The Chemistry of Cyclopentadienyl Titanium and Vanadium Complexes with B- and C-functionalized Carborane-thiols, [C2<\/sub>B10<\/sub>H12-n<\/sub>(SH)n<\/sub>] (n = 2 or 3): S. Bairagi, D.K. Patel, D. Chatterjee, M. Ku\u010der\u00e1kov\u00e1, J. Mach\u00e1\u010dek, T. Base, T. Pradeep and S. Ghosh, Chem. Sci.<\/em>, 2025<\/strong>, 16<\/em>, 14127. [pdf<\/a>] [ Most popular 2025 inorganic chemistry articles<\/em><\/a>] & [2025 Chemical Science HOT Article Collection<\/em><\/a>]<\/li>\n
  3. Cooperative B-H Bond Activation: A Direct Route to Monometallic Diborane(5) and Dihydroborate Complexes: S. Saha, P. Chakrabortty, and S. Ghosh, Chem. Eur. J.<\/em>, 2025<\/strong>, 31<\/em>, e02125. [pdf<\/a>]<\/li>\n
  4. Syntheses, Structures, and Theoretical Insights of Homobimetallic Ruthenium Complexes Comprising Mercaptobenzothiazolyl Ligand: A. Ahmad, U. Gupta, S. Jaiswal and S. Ghosh, Organometallics<\/em>, 2025<\/strong>, 44<\/em>, 1362. [pdf<\/a>]<\/li>\n
  5. Diborane and Bis(boryl) Complexes of Osmium Stabilized in the Coordination Sphere of [Cp*Os] (Cp* = \u03b7<\/i>5<\/sup>-C5<\/sub>Me5<\/sub>): D. Chatterjee, S. Shyamal and S. Ghosh, Organometallics<\/em>, 2025<\/strong>, 44<\/em>, 1075. [pdf<\/a>]<\/li>\n
  6. Heavier Chalcogenate-Bridged Manganese Carbonyl Complexes: Synthesis, Reactivity and Electrochemical Investigation: S. Mishra, T. Dolkar, A. Pareek, R. Maji, A. Dutta and S. Ghosh, Chem. Asian J.<\/em>, 2025<\/strong>, 0<\/em>, e202401820. [pdf<\/a>]<\/li>\n
  7. Hypoelectronic Titanaboranes: Icosahedral and Tetracapped Tetrahedral Clusters Comprising Bridging Hydrides: S. Bairagi, D. Chatterjee, S. Giri and S. Ghosh, Chem. Commun.<\/em>, 2025<\/strong>, 61<\/em>, 3696.[pdf<\/a>] [Featured Structure Friday<\/em><\/em><\/a>]<\/li>\n
  8. Cooperative B-H Activation: Ligand Diversity in Groups 6 and 8 Transition Metal \u03ba2<\/sup>–N,E<\/em>-chelated Complexes (E = S or Se): S. Saha, S. Mohapatra, M. Kumar, D. Yadav and S. Ghosh, Inorg. Chem.<\/em>, 2025<\/strong>, 64<\/em>, 2618. [pdf<\/a>]<\/li>\n
  9. A Pair of Dinuclear Fe(II) Enantiomers: Syntheses and Structures of \u039b\u0394\/\u0394\u039b-Bis(Dihydridoborate) Complexes: U. Kaur, S. Gayen, H. Sharma, K. Vanka and S. Ghosh, Chem. Eur. J.<\/em>, 2025<\/strong>, 31<\/em>, e202404469. [pdf<\/a>]<\/li>\n
  10. Recent Advances of B-P Coupling Reactions: Conventional and Efficient Alternative Routes: S. Gayen and S. Ghosh, Eur. J. Inorg. Chem.<\/em>, 2025<\/strong>, 28<\/em>, e202400732. [pdf<\/a>]<\/li>\n
  11. The Insertion Reactions of GeCl2<\/sub> with Mono- and Bis-\u03ba<\/em>2<\/sup>-N,S-Chelated Ru(II) Complexes: A. Ahmad, F. Assanar, U. Gupta, P. Shukla, S. Nagendran and S. Ghosh, Eur. J. Inorg. Chem.<\/em>, 2025<\/strong>, 28<\/em>, e202400660. [pdf<\/a>]<\/li>\n
  12. Stabilization of Ethane-like Dianionic Diborane(6) in Monometallic Titanium Complexes and its Subsequent B(sp3<\/sup>)-B(sp3<\/sup>) Bond Cleavage: S. Bairagi, S. Giri, G. Joshi, E. D. Jemmis and S. Ghosh, Angew. Chem. Int. Ed.<\/em>, 2025<\/strong>, 64<\/em>, e202417170. [pdf<\/a>]<\/li>\n
  13. Osmium Borallyl Complexes: Structure and Bonding of [L(PPh3<\/sub>)(H)Os(\u03b7<\/em>n<\/sup>-B3<\/sub>H5<\/sub>L\u20192<\/sub>)], (L = H, Cp*; n = 5, 3; L\u2019 = C5<\/sub>H4<\/sub>NS, H)(Cp* = \u03b7<\/em>5<\/sup>-C5<\/sub>Me5<\/sub>): S. Gayen, S. Shyamal, F. Assanar and S. Ghosh, Organometallics<\/em>, 2024<\/strong>, 43<\/em>, 2935. [Most popular 2024 inorganic chemistry articles.<\/em><\/a>] [pdf<\/a>]<\/li>\n
  14. Osmaborane Clusters with B4 and B5 Rings Stabilized in the Coordination Sphere of {OsLn<\/sub>} (Ln<\/sub> = \u03b7<\/em>5<\/sup>-C5<\/sub>Me5<\/sub> or H2<\/sub>(PPh3<\/sub>)2<\/sub>): S. Shyamal, D. Chatterjee, K. Kar and S. Ghosh, Inorg. Chem.<\/em>, 2024<\/strong>, 63<\/em>, 21838. [pdf<\/a>]<\/li>\n
  15. Small Ring Molecules Comprising 3-6 Boron Atoms: An Account on Synthesis, Structure, and Orbital Engineering: S. Kar, S. Bairagi, G. Joshi, E. D. Jemmis, H. Himmel and S. Ghosh, Acc. Chem. Res.<\/em>, 2024<\/strong>, 57<\/em>, 2901. [pdf<\/a>]<\/li>\n
  16. Metal-Rich Fused Clusters: Syntheses, Structures and Bonding of Heteronuclear Condensed Metallaboranes: S. Jaiswal, A. N. Pradhan and S. Ghosh, Organometallics<\/em>, 2024<\/strong>, 43<\/em>, 2086. [pdf<\/a>]<\/li>\n
  17. Quantifying Variation in Cooperative B-H Bond Activations by Os(II) and Os(III) \u03ba<\/em>2<\/sup>-N,S-chelated Complexes: Same, but Different: S. Gayen, F. Assanar, S. Shyamal, P. D. Dorairaj and S. Ghosh, Chem. Sci.<\/em>, 2024<\/strong>, 15<\/em>, 15913. [pdf<\/a>]<\/li>\n
  18. Beyond S and Se: Electrocatalytic Hydrogen Production by Tellurolate-Bridged Co(III)-Mn(I) Heterodinuclear Complexes: S. Mishra, T. Dolkar, A. Pareek, R. Bonthapally, D. Maity, A. Dutta and S. Ghosh, Inorg. Chem.<\/em>, 2024<\/strong>, 63<\/em>, 16918. [pdf<\/a>]<\/li>\n
  19. Reactivity of [(Cp*<\/sup>CoPh)(Cp*<\/sup>Co)(\u03bc<\/em>-TePh)(\u03bc<\/em>–\u0138<\/em>2<\/sup>-Te,H-TeBH3<\/sub>)] towards [M(CO)5<\/sub>\u00b7THF] (M = Mo and W), CS2<\/sub> and [Fe2<\/sub>(CO)9<\/sub>]: A. N. Pradhan, S. Bairagi and S. Ghosh, Inorg. Chem.<\/em>, 2024<\/strong>, 63<\/em>, 15648. [pdf<\/a>]<\/li>\n
  20. Polyhedral and Macropolyhedral Metal-Rich Cobaltaboranes: A 25-Vertex Hourglass-Shaped Cluster: S. Giri, C. Nandi, P. Nampi, R. M. Parmar and S. Ghosh, Inorg. Chem.<\/em>, 2024<\/strong>, 63<\/em>, 11639. [pdf<\/a>] (Invited article for ACS Special Issue Celebrating the CRSI 25th Anniversary)<\/em><\/li>\n
  21. Synthesis, Structures and Bonding of Group 6 Thio-complexes: S. Mohapatra, A. Haridas, M. Kumar and S. Ghosh, Inorg. Chim. Acta<\/em>, 2024<\/strong>, 571<\/em>, 122205. [pdf<\/a>] (Invited article for Special issue in honour to Professor Ashutosh Ghosh)<\/em><\/li>\n
  22. Bimetallic Perthiocarbonate Complexes of Cobalt: Synthesis, Structure and Bonding: A. N. Pradhan, S. Mishra, U. Kaur, B. K. Rout, J.-F. Halet and S. Ghosh, Molecules<\/em>, 2024<\/strong>, 29<\/em>, 2688. [pdf<\/a>] (Invited article for Exclusive Feature Papers in Inorganic Chemistry 2.0)<\/em><\/li>\n
  23. Borate ligand derived from CS2<\/sub> unveiling ruthenium dithioformate and trithia-borinane complexes: A. Ahmad, S. Gayen, S. Mishra, Z. Afsan, L. Vendier and S. Ghosh, Polyhedron<\/em>, 2024<\/strong>, 256<\/em>, 116986. [pdf<\/a>] (Invited article for ACCC9 Special Issue)<\/em><\/li>\n
  24. Syntheses, Structures, and Bonding of Boron Containing Niobium and Ruthenium Clusters Stabilized by Chalcogens: S. Bairagi, D. Chatterjee, A. De, M. Cordier, T. Roisnel and S. Ghosh, J. Organomet. Chem.<\/em>, 2024<\/strong>, 1012<\/em>, 123126. [pdf<\/a>] (Invited article for WT Wong Special Issue)<\/em><\/li>\n
  25. Synthesis, Structure and Bonding of Group 8 Transition Metal Germyl Complexes, [Cp*<\/sup>M {\u03ba<\/em>2<\/sup>-Ge,S-GeCl2<\/sub>C7<\/sub>H4<\/sub>NS2<\/sub>}(PPh3<\/sub>)] (M = Ru or Os): S. Saha, F. Assanar, A. Ahmad, A. Bains, S. Nagendran and S. Ghosh, Organometallics<\/em>, 2024<\/strong>, 43<\/em>, 718. [pdf<\/a>]<\/li>\n
  26. Bridging Bis(boryl) and Borylene Species Stabilized in the Coordination Sphere of Ruthenium Metals: U. Kaur, S. Jaiswal, M. Cordier, B. P. T. Fokwa and S. Ghosh, Organometallics<\/em>, 2024<\/strong>, 43<\/em>, 617. [pdf<\/a>]<\/li>\n
  27. Rule Breaker Boron Clusters: A New Class of Hypoelectronic Osmaborane Clusters [(Cp*<\/sup>Os)2<\/sub>Bn<\/sub>Hn<\/sub>] (n = 6-10): K. Kar, S. Kar and S. Ghosh, Chem. Sci.<\/em>, 2024<\/strong>, 15<\/em>, 4179. [pdf<\/a>]<\/li>\n
  28. Doubly Base-Stabilised Diborane(4) and Borato-Boronium Species and Their Chemistry with Chalcogens: A. Ahmad, S. Gayen, S. Mishra, Z. Afsan, S. Bontemps and S. Ghosh, Inorg. Chem.<\/em>, 2024<\/strong>, 63<\/em>, 3376. [pdf<\/a>]<\/li>\n
  29. Hetero-trimetallic Complexes Comprising Bridging Boryl and Borylene Ligands: An Experimental and Theoretical Study: S. Bairagi, S. Giri, D. K. Patel, D. Luong, B. P. T. Fokwa and S. Ghosh, Dalton Trans.<\/em>, 2024<\/strong>, 53<\/em>, 3191. [pdf<\/a>]<\/li>\n
  30. Metal Rich Metallaboranes: Synthesis, Structure and Bonding of pileo<\/em>-[(Cp*<\/sup>Ru)2<\/sub>M(CO)3<\/sub>(\u00b5<\/em>-H)(\u00b5<\/em>-E)(\u00b5<\/em>3<\/sub>-BH)B2<\/sub>H5<\/sub>] (M = Mo, W, E = CO, and M = Mn, E = H) Clusters: A. N. Pradhan, S. Jaiswal, M. Cordier, J.-F. Halet and S. Ghosh, Inorganics<\/em>, 2024<\/strong>, 12<\/em>, 7. [pdf<\/a>] (Invited article for a special issue on Boron Chemistry: Fundamentals and Applications)<\/em><\/li>\n
  31. B-P Coupling: Metal Stabilized Phosphinoborate Complexes: S. Gayen, S. Shyamal, S. Mohapatra, P. K. S. Antharjanam and S. Ghosh, Chem. Eur. J.<\/em>, 2024<\/strong>, 30<\/em>, e202302362. [pdf<\/a>] (Invited article for a special issue on Special Collection: p-block elements)<\/em><\/li>\n
  32. Transition Metal Triple-decker Sandwich Complexes Containing Group 13 Elements: D. Chatterjee, S. Bairagi and S. Ghosh, Chem. Asian J.<\/em>, 2024<\/strong>, 12<\/em>, e202300864. [pdf<\/a>]<\/li>\n<\/ol>\n<\/div>\n\t\t<\/div><\/div><\/div><\/div>\n\n\n

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