Dr. M. V. Sangaranarayanan

Professor

Email :sangara@iitm.ac.in
Phone: 2257 4209

Academic profile


  • Research Interest:

    Statistical mechanics of electrochemical interfaces, phase transitions, chemically modified electrodes, diffusion at ultramicroelectrodes.

    List of Publications (From 2001 Onwards ):

    (A) BOOKS

    1. C. KALIDAS AND M. V. SANGARANARAYANAN
      NON- EQUILIBRIUM THERMODYNAMICS - PRINCIPLES AND APPLICATIONS - MACMILLAN INDIA LTD 2002

    2. M.V.SANGARANARAYANAN AND MAHADEVAN
      TEXTBOOK OF PHYSICAL CHEMISTRY UNIVERSITIES PRESS INDIA (2011)

    (B) JOURNALS

    No
    Authors
    Title
    Journal
    1. J.Uma Maheswari and M.V.Sangaranarayanan Non-equilibrium thermodynamics formalism for charge transport through redox polymer electrodes J.Phys.Chem B
    105(2001) 2465 to 2473
    2. S.Harinipriya and
    M.V.Sangaranarayanan
    Electron transfer reactions at metal electrodes : Influence of work function on free energy of activation and exchange current density J.Chem.Phys.
    115(2001)6173 to 6178.
    3. S.Harinipriya and
    M.V.Sangaranarayanan
    Two-dimensional condensation of nucleobases at mercury/aqueous solution interface-A structural perspective J. Colloid and Interface Science
    250(2002) 201 to 212.
    4. S.Harinipriya and
    M.V.Sangaranarayanan
    Influence of work function on electron transfer processes at metals: Application to Hydrogen Evolution Reaction Langmuir
    18(2002)5572 to 5578.
    5. S.Harinipriya and M.V. Sangaranarayanan Hydrogen Evolution Reaction on electrodes: Influence of work function, dipolar adsorption and desolvation energies J. Phys. Chem. B
    106 (2002) 8681 to 8688.
    6. S.Harinipriya and M.V. Sangaranarayanan Hardness of metals from electron transfer reactions at electrode surfaces J.Chem.Phys 117(2002)8959 to 8965.
    7. S.Harinipriya and M.V. Sangaranarayanan Estimation of the electron affinities of nucleobases using thermochemical data and structural considerations J.Mol.Structure 644(2003)133 to 138.
    8. S.Harinipriya and M.V. Sangaranarayanan Estimation of activation energies for heterogeneous catalytic processes from thermodynamic and structural considerations J.Mol.Catalysis A
    207(2004) 105 to 114.
    9. S.Harinipriya and M.V. Sangaranarayanan Order-disorder transitions of water dipoles at mercury electrodes Indian J. Chem A
    42 (2003) 965 to 967.
    10. S.Harinipriya and M.V. Sangaranarayanan Electron transfer processes across liquid/liquid interfaces-Estimation of the equilibrium free energy of activation J.Phys.Chem B 108(2004)1660 to 1666
    11. V. Sudha and M.V. Sangaranarayanan Underpotential Deposition of Metals from Thermodynamic and Structural Considerations J.Phys.Chem. B
    106 (2002) 2699 to 2707.
    12. V.Sudha and M.V. Sangaranarayanan Underpotential Deposition of metals from Thermodynamic and structural Considerations –Part –II – Non-aqueous solvent J. Phys. Chem B
    107 (2003) 3907 to 3913.
    13. M.Arun Prasad and M.V. Sangaranarayanan Analysis of diffusion layer thickness, equivalent circuit and conductance behaviour for reversible electron
    transfer processes in linear sweep voltammetry
    Electrochim.Acta
    49(2004) 445-453
    14. M.Arun Prasad and
    M.V.Sangaranarayanan
    Evaluation of the Gibbs free energy of transfer of electrolytes from aqueous to organic solvents-A novel application of the quadratic activation-driving force relation Chem. Phys. Lett
    382(2003)325 to 331
    15. S.Harinipriya, V.Sudha and
    M.V.Sangaranarayanan
    Dehydration energies of alkali metal halides- A new simulation methodology involving mean nearest neighbor distances and thermodynamic forces Langmuir
    20(2004) 1871- 1876
    16. S.Harinipriya and
    M.V.Sangaranarayanan
    Estimation of exchange current density for ferric/ferrous reaction-Influence of ionic desolvation.. J. Colloid and Interface Science 273(2004) 247 to 255
    17. M.ArunPrasad,V.Aravind
    And
    M.V.Sangaranarayanan
    Doping behaviour of ions on polypyrrole-coated Platinum in binary solvents Proc. Indian National Science Academy –Special issue on Electrochemistry
    70 A(2004)463 to 468.
    18. M.Arun Prasad and
    M.V.Sangaranarayanan
    Current function for irreversible electron transfer processes in linear sweep voltammetry for reactions obeying Marcus kinetics Chem.Phys.Letters 387(2004) 317 to 321

    19. M.Arun Prasad and
    M.V.Sangaranarayanan
    Formulation of a simple analytical expression for
    irreversible electron transfer processes in LSV and its experimental verification
    Electrochimica Acta
    49(2004) 2569 to 2579
    20. M.Arun Prasad and
    M.V.Sangaranarayanan
    Solvent effect on the electrochemical reductive cleavage of CCl4 Chemical Physics Letters
    390(2004) 261-267
    21. M.Arun Prasad and
    M.V.Sangaranarayanan
    Cleavage of an aromatic carbon-heteroatom bond in a single step or successive steps?-A mechanistic distinction in the reduction of 5-bromo –1,3-dichloro –2-iodobenzene Tetrahedron Letters
    45(2004) 4741 to 4744
    22. M.Arun Prasad and
    M.V.Sangaranarayanan
    Electrochemical reductive cleavage of carbon tetrachloride in aqueous-non aqueous binary solvents Journal of Electroanalytical Chemistry
    569(2004) 127 to 134
    23. V.Sudha ,S.Harinipriya and
    M.V.Sangaranarayanan
    Hydration energies of trihalides of Lanthanide and actinide series-a novel simulation methodology Journal of Molecular structure (Theochem)
    683(2004) 159 to 165
    24. V.Sudha ,S.Harinipriya and
    M.V.Sangaranarayanan
    A simple simulation methodology for estimation of dehydration energies and surface potentials of concentrated NaCl solutions J. Colloid and Interface Science 280(2004) 139 to 148
    25. M.Arun Prasad and
    M.V.Sangaranarayanan
    Electrochemical reductive cleavage of carbon-halogen bonds in 5-bromo-1,3-dichloro-2-iodobenzene Tetrahedron 60(2004)
    10967 to 10972.
    26. M.Arun Prasad and
    M.V.Sangaranarayanan
    5-bromo-1,3-dichloro-2-iodobenzene Acta Crystallographica
    E60(2004) o 1933 to o1934.
    27. S.Harinipriya and M.V. Sangaranarayanan Stability of scanning tunneling microscopy tip-induced bimetallic nanoclusters: Influence of hardness and composition on the cohesive energies Journal of Physical Chemistry
    B108(2004)13944-13947.
    28. T.C.Girija and
    M.V.Sangaranarayanan
    Anion-induced adsorption of thallium complex on silver electrodes J. Colloid and Interface Science
    282(2005) 92-101
    29. T.C.Girija and
    M.V.Sangaranarayanan
    Extraction of Electrochemical Quartz Crystal Microbalance Frequencies from cyclic Voltammetric data Journal of Solid State Electrochemistry
    9(2005)621-626
    30. M.Arun Prasad and
    M.V.Sangaranarayanan
    Distinction between stepwise and concerted mechanisms in reductive cleavage reactions Tetrahedron
    61(2005) 1785-1791
    31. M.Arun Prasad and
    M.V.Sangaranarayanan
    4-bromo-2,6-dichloroaniline Acta Crystallographica E 61(2005) o758-o759
    32. V.Sudha,S.Harinipriya and
    M.V.Sangaranarayanan
    Dehydration energies of alkaline earth metal halides-a novel simulation methodology Chemical Physics
    310(2005) 59-66
    33. V.Sudha,S.Harinipriya and
    M.V.Sangaranarayanan
    Hydration energies of Thallium (I) halides – A novel simulation
    Methodology
    Journal of Molecular Structure
    750(2005)621-626
    34. M.Arun Prasad and
    M.V.Sangaranarayanan
    Hammett-type relationship for the cleavage of radical anions of aromatic chlorides and bromides Tetrahedron
    61(2005) 3755-3758
    35. T.C.Girija and
    M.V.Sangaranarayanan
    Development of Electrochemical Supercapacitors using Underpotential Deposition of thallium on silver Indian J. Chemistry
    Section A 44(2005)1395-1397
    36. M.Arun Prasad and
    M.V.Sangaranarayanan
    Electrochemical reductive cleavage of carbon-chlorine bond in
    1-chloro,2,4-dinitrobenzene
    Electrochim.Acta
    51(2005)242-246
    37. M.Arun Prasad and
    M.V.Sangaranarayanan
    Evidence for the formation of radical anion in the reductive cleavage of carbon-bromine bond Chemical Physics Letters 414(2005)55-60
    38. V.Sudha and
    M.V.Sangaranarayanan
    Underpotential Deposition of metals-Progress and Prospects in modeling Journal of Chemical Sciences
    117(2005) 207-218
    39. T.C.Girija and
    M.V.Sangaranarayanan
    Underpotential deposition of Tl on Ag in the presence of bromide ions - Estimation of specific capacitance for design of electrochemical supercapacitors Journal of Applied
    Electrochemistry
    36(2006) 531-538
    40. M.Arun Prasad and
    M.V.Sangaranarayanan
    Linear kinetic and free energy correlations for intra molecular dissociative electron transfers CHEMICAL PHYSICS LETTERS 421 (2006) 193-197
    41. T.C.Girija and
    M.V.Sangaranarayanan
    Investigation of polyaniline-coated stainless steel electrodes for electrochemical supercapacitors SYNTHETIC METALS 156 (2006) 244-250
    42. A.Muthukrishnan and
    M.V.Sangaranarayanan
    Differential capacitance of liquid/liquid interfaces - A lattice gas model approach JOURNAL OF COLLOID AND INTERFACE SCIENCE 296 (2006) 624-633
    43. S.Harinipriya and
    M.V.Sangaranarayanan
    Analysis of electron transfer processes across liquid/liquid interfaces: Estimation of free energy of activation using diffuse boundary model LANGMUIR
    22 (2006) 1347-1355
    44.

    T.C.Girija and
    M.V.Sangaranarayanan

    Analysis of Polyaniline-based Nickel electrodes for Electrochemical supercapacitors

    Journal of Power Sources 159(2006)705
    45.

    T.C.Girija and
    M.V.Sangaranarayanan

    Polyaniline-based Nickel electrodes for Electrochemical supercapacitors-Influence of Triton-X-100

    Journal of Power Sources 159(2006) 1519

    46.

    V.Sudha,S.Harinipriya and M.V.Sangaranarayanan

    Estimation of desolvation energies of lanthanum and uranium trihalides in heavy water

    J.Mol.Structure-Theochem
    765(2006) 71.

    47.

    A.Muthukrishnan  and
    M.V.Sangaranarayanan

    Hydration energies of C60 and C70 fullerenes-A novel Monte Carlo simulation study

    Chemical Physics
    331(2007) 200

    48.

    A.Muthukrishnan and
    M.V.Sangaranarayanan

    Electrochemical reduction of carbon-fluorine bond in 4-fluorobenzonitrile-Mechanistic Analysis employing Marcus-Hush quadratic activation-driving force relation

    Chem.Phys.Lett
    446(2007)297-303.

    49.

    R.Ramya and
    M.V.Sangaranarayanan

    Analysis of polypyrrole-coated stainless steel electrodes –Estimation of specific capacitances and construction of equivalent circuits

    J.Chem.Sciences
    120(2008)25-31

    Recent Publications

     

    No
    Authors
    Title
    Journal
    50.

    Richa Sethi and
    M.V.Sangaranarayanan

    Non-Equilibrium Thermodynamics formalism for Marcus theory of heterogeneous and self-exchange electron transfer rate constants

    J.Phys.Chem A
    112(2008)4308-4313

    51.

    A.Muthukrishnan and
    M.V.Sangaranarayanan

    Mechanistic Analysis of the reductive cleavage of carbon-halogen bonds in halopentafluorobenzenes

    J.Electrochem.Soc 156(2009) F23- F28.

    52.

    G.Nandhini and
    M.V.Sangaranarayanan

    Extraction of electron density profiles from X-ray reflectivity data of liquid metals

    Chem.Phys.Lett
    470(2009)224-227

    53.

    G.Nandhini and
    M.V.Sangaranarayanan

    Partition function of nearest neighbour Ising models-Some new insights

    J.Chem.Sciences
    121(2009)595

    54.

    A.Muthukrishnan and
    M.V.Sangaranarayanan

    Analysis of C-F bond cleavages in methylfluorobenzoates-Fragmentation and dimerization of anion radicals using convolution potential sweep voltammetry

    Electrochim Acta
    55(2010)1664

    55. A.Muthukrishnan M.V.Sangaranarayanan VPBoyarskiy and IABoyarskaya

    Regioselective electrochemical reduction of 2,4-dichlorobiphenyl - Distinct standard reduction potentials for carbon-chlorine bonds using convolution potential sweep voltammetry

    Chem.Phys Lett 490(2010)148.

    56. VPBoyarskiy M.V. Sangaranarayanan,TS Khaibulova and IABoyarskaya Reduction of Mono- and Dichlorobiphenyls with Sodium-Naphthalene Complex

    Russian  Journal of General Chemistry
    80(2010)800