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  1. Reaction kinetics of Cl atoms with limonene: An experimental and theoretics study. Manas Ranja Dash, B. Rajakumar. Atmos. Environ. 2104, 99, 183
  2. Theoretical investigations on the kinetics of H-abstraction reactions from CF3CH(OH)CF3 by OH radicals.;Srinivasulu, G., Rajakumar, B.; Journal of Physical Chemistry A, Volume 117, Issue 22, 2013, Pages 4534-4544.
  3. Rate coefficients and reaction mechanism for the reaction of OH radicals with (E)-CF 3CH=CHF, (Z)-CF 3CH=CHF, (E)-CF3CF=CHF, and (Z)-CF 3CF=CHF between 200 and 400 K: Hybrid density functional theory and canonical variational transition state theory calculations. Balaganesh,M.,Rajakumar, B.; Journal of Physical Chemistry A, Volume 116, Issue 40, 11 October 2012, Pages 9835-9842.;Balaganesh,M.,Rajakumar, B.; Journal of Physical Chemistry A, Volume 116, Issue 40, 11 October 2012, Pages 9835-9842.
  4. Experimental and theoretical rate coefficients for the gas phase reaction of beta-Pinene with OH radical. Dash, M.R., Rajakumar, B; Atmospheric Environment, Volume 79, November 2013, Pages 161-171.
  5. Experimental and theoretical study on thermal decomposition of methyl butanoate behind reflected shock waves. A. Parandaman, M. Balaganesh and B. Rajakumar; RSC Adv., 2015, 5, 86536-86550.
  6. Rate coefficients for the gas-phase reaction of OH radical with alpha-pinene: An experimental and computational study. Dash, M.R., Balaganesh,M., Rajakumar, B.; Molecular Physics, Volume 112, Issue 11, 3 June 2014, Pages 1495-1511.
  7. Abstraction and addition kinetics of C2H radicals with CH4, C2H6, C3H8, C2H4, and C3H6: CVT/SCT/ISPE and hybrid meta-DFT methods; Dash, M.R., Rajakumar, B.; Physical Chemistry Chemical Physics, Volume 17, Issue 5, 7 February 2015, Pages 3142-3156.
  8. Thermal Decomposition of 2-Pentanol: A Shock Tube Study and RRKM Calculations Parandaman Arathala, and Balla Rajakumar,J. Phys. Chem. A, DOI: 10.1021/acs.jpca.6b06386
  9. Kinetic investigations of chlorine atom initiated photo oxidation reactions of 2,3-dimethyl-1,3- butadiene in the gas phase: an experimental and theoretical study, S. Vijayakumar and B. Rajakumar, RSC Adv., 2016, 6, 67739
  10. Theoretical investigations of the gas phase reaction of limonene (C10H16) with OH radical; Dash,M.R., Rajakumar,B.; Molecular Physics, 1 February 2015, 14p
  11. Experimental and computational investigation on the gas phase reaction of p-cymene with Cl atoms; Dash, M.R., Srinivasulu, G., Rajakumar, B.; Journal of Physical Chemistry A, Volume 119, Issue 4, 29 January 2015, Pages 559-570.
  12. Experimental and computational investigation on the gas phase reaction of ethyl formate with Cl atoms. Balaganesh, M., Dash, M.R., Rajakumar, B.; Journal of Physical chemistry A , Volume 118, Issue 28, 17 July 2014, Pages 5272-5278.
  13. Thermal decomposition of 1-chloropropane behind the reflected shock waves in the temperature range of 1015-1220 K: Single pulse shock tube and computational studies. Sudhakar, G., Rajakumar, B.; Journal of Chemical Sciences, Volume 126, Issue 4, July 2014, Pages 897-909.
  14. Shock tube study and RRKM calculations on thermal decomposition of 2-chloroethyl methyl ether, A. Parandaman and B. Rajakumar, Combustion and Flame, 186 (2017), 263-276
  15. Experimental and RRKM investigations on the degradation of ethyl formate”, B. Rajakumar, M. Balaganseh and A. Parandaman, ChemistrySelect 2017, 2, 11603 – 11614.
  16. Theoretical investigations on the kinetics of p-cymene + OH reaction. Dash, M.R., Rajakumar, B.; Chemical Physics Letters, Volume 597, 28 March 2014, Pages 75-85.
  17. Mechanism, kinetics and atmospheric fate of CF3CHCH2, CF3CFCH2, and CF3CFCF2 by its reaction with OH-radicals: CVT/SCT/ISPE and hybrid meta-DFT methods. Balaganesh,M., Rajakumar, B.; Journal of Molecular Graphics and Modelling, Volume 48, March 2014, Pages 60-69
  18. Gas Phase Kinetics of 2, 2, 2-trifluoroethylbutyrate with Cl Atom: An Experimental and Theoretical Study. Srinivasulu Gonu and Balla Rajakumar, J.Phys.Chem.A 2015, 119, 9294-9306
  19. Measuring Temperature of Reflected Shock Wave Using a Standard Chemical Reaction, M. Kiran Singh, B. Rajakumar and E. Arunan, Journal of the Indian Institute of Science, 2016, 96,1. Foster et. al.
  20. Kinetic investigations on the chlorine atom sensitized photo-oxidization reactions with a series of 1-alkenes in troposphere.” S. Vijayakumar and B. Rajakumar, Environ. Sci. Pollut. Res. 2018, 25, 4387-4405.
  21. Experimental and computational kinetic investigations for the reactions of Cl atoms with unsaturated ketones in gas phase. S. Vijayakumar, Avinash Kumar and B. Rajakumar. New J. Chem., 2017,41, 14299-14314.
  22. Is H Atom Abstraction Important in the Reaction of Cl with 1-Alkenes? M. P. Walavalkar, S. Vijayakumar, A. Sharma, B. Rajakumar and S. Dhanya, J.Phys.Chem.A, 2016, 120, 4096-4107.
  23. Rate coefficients for hydrogen abstraction reaction of pinonaldehyde (C10H16O2) with Cl atoms between 200 and 400 K: A DFT study, G SRINIVASULU and B RAJAKUMAR, J. Chem. Sci., 2016, 128, 977-989.
  24. Kinetics of the thermal decomposition of tetramethylsilane behind the reflected shock waves between 1058 and 1194 K, A. PARANDAMAN and B. RAJAKUMAR, J. Chem. Sci., 2016, 128, 573-588.
  25. Addition and abstraction kinetics of H atom with propylene and isobutylene between 200 and 2500 K: A DFT study, A. Parandaman and B. Rajakumar, Chemical Physics, 491(2017), 82-94.
  26. Cl initiated photo oxidation reactions of methyl propionate in atmospheric condition” C. B. Ramya and B. Rajakumar. Env. Sci. Poll. Res. 2018. (Accepted)
  27. Kinetic investigations on the gas phase reaction of 2,2,2-trifluoroethylbutyrate with OH radicals: An experimental and theoretical study. G. Srinivasulu, S. Vijayakumar and B. Rajakumar Chem. Sel. 2018. (Accepted).
  28. Kinetic investigations of Cl atoms initiated photo oxidation reactions of cyclic unsaturated hydrocarbons in the gas phase: an experimental and theoretical study, S.Vijayakumar, C.B Ramya, Avinash Kumar and B.Rajakumar, N. J. Chem. 2017, 41, 7491 – 7505.
  29. Experimental and theoretical investigations on the reaction of 1,3-butadiene with Cl atom in the gas phase, S.Vijayakumar and B.Rajakumar, J. Phys. Chem. A. 2017, 121, 1976−1984.
  30. An Experimental and Computational Study on the Cl Atom Initiated Photo-Oxidization Reactions of Butenes in the Gas Phase, S.Vijayakumar and B.Rajakumar, J. Phys. Chem. A, 2017, 121, 5487–5499
  1. Chemical kinetics studies at high temperature using Shock Tubes B.Rajakumar, D. Anandraj, K. P. J. Reddy and E. Arunan. J. Ind. Inst. Sci. 2002, 82, 37.
  2. Thermal decomposition of 2-fluoroethanol: A Shock Tube and ab initio study. B.Rajakumar, K. P. J. Reddy, E. Arunan. J. Phys. Chem. A. 2003, 107, 9782- 9793 Poly(Aryl Ether) based Borogels: A New Class of Materials for Hosting Nanoparticles and Sensing Anions
  3. Rate Coefficients for the Reaction of hydroxyl radical with FCH2CH2OH between 250 and 355K; B. Rajakumar, Robert W. Portmann, James B. Burkholder, A. R. Ravishankara. Phys. Chem. Chem. Phys. 2005, 7, 2498-2505.
  4. Unimolecular HCl elimination from 1,2-dichloroethane: A Single Pulse Shock Tube and ab initio study. B.Rajakumar, K. P. J. Reddy, E. Arunan. J. Phys. Chem. A 2002, 106, 8366.
  5. Ab initio, DFT and transition state theory calculations on 1, 2-HF, HCI and CIF elimination reactions from CH2FCH2Cl. B.Rajakumar, E. Arunan. Phys. Chem. Chem. Phys. 2003, 5, 3897-3904.
  1. Kinetics of the reaction of OH radical with CF3CH2CH3, CHF2CHFCHF2 and CF3CHFCHF2 in the temperature range of 238-375K; B. Rajakumar, R. W. Portmann, James B. Burkholder, A. R. Ravishankara. J. Phys. Chem. A. 2006, 110, 6724.
  2. Rate coefficients for the relaxation of OH(v=1) by O2at Temperatures from 204-371 K and by NO2 from 243-372 K.. David C. McCabe, B.Rajakumar, I. W. M. Smith, A. R. Ravishankara. Chem. Phys. Lett. 2006, 421, 111-117
  3. Kinetics of Quenching of OH (v=1) and OD (v=1) by H2O and D2O from 260 to 370K; K. Yuvaraj, D. K. Roy, V. P. Anju, B. Mondal, B. Varghese and S. Ghosh, Dalton Trans., 2014, 43, 17184 David C. McCabe, B.Rajakumar, P. Marshall, I. W. M. Smith, A. R. Ravishankara. Phys. Chem. Chem. Phys. 2006, 8, 4563.
  4. Kinetics of OH radical reaction with CH3CHFCH2F (HFC-245eb) between 200 and 400K: G3MP2, G3B3 and Transition State Theory Calculations Mohamad Akbar Ali, B.Rajakumar. Journal of Molecular Structure: THEOCHEM, 2010, 949, 73.
  5. Rate coefficients for the reactions of the acetyl radical, CH3CO, with Cl2 between 253 and 384K Thomasz Gierczak, B.Rajakumar, John E. Flad, James B. Burkholder. Int. J. Chem. Kinet. 2009, 41, 543-553.
  6. The CH3CHO quantum yield in the 248 nm photolysis of acetone, methyl ethyl ketone, and biacetyl B.Rajakumar, Thomasz Gierczak, John E. Flad, A. R. Ravishankara, James B. Burkholder. J. Photo. Chem. Photo. Biol. A: Chemistry, 2008, 199, 336-344.
  7. Visible absorption spectrum of acetyl radical B. Rajakumar, Thomas Gericzak, John E. Flad, A. R. Ravishankara, James B. Burkholder, J. Phys. Chem. A. 2007, 111, 8950-8958. (Cover page Article, issue 37).
  8. Kinetic study of the reaction of the acetyl radical, CH3CO, with O3 using cavity ring-down spectroscopy Thomasz Gierczak, B.Rajakumar, John E. Flad, James B. Burkholder. Chem. Phys. Lett. 2010, 484, 160-164.
  9. Rate Coefficients for the Reactions of OH with n-propanol and iso-propanol between 235 and 376K B.Rajakumar, David C. McCabe, Ranajit K. Talukdar, A. R. Ravishankara, Int. J. Chem. Kinet. 2010, 43, 10.g
  10. Rate coefficients for the Reaction of OH with CF3CH2CH3 (HFC-263fb) between 200 and 400K: ab initio, DFT and Transitions State Theory Calculations Mohamad Akbar Ali, B. Rajakumar. J. Comp. Chem. 2010, 31, 500-509.
  1. ISSW 30
  2. Kinetic parameters of abstraction reactions of OH radical with ethylene, fluoroethylene, cis- and trans-1,2-difluoroethylene and 1,1-difluoroethylene, in the temperature range of 200-400 K: Gaussian-3/B3LYP theory,Ali, M.A., Upendra, B., Rajakumar, B.Chemical Physics Letters, Volume 511, Issue 4-6, 5 August 2011, Pages 440-446.
  3. Abstraction Kinetics of H-Atom by OH Radical from Pinonaldehyde: Ab Initio and Transition-State Theory Calculations; Manas Ranjan Dash and B. Rajakumar; J. Phys. Chem. A, 2012, 116, 5856-5866.
  4. Kinetic parameters of OH radical reaction with CH3OCH2F (HFE-161) in the temperature range of 200 400 K: Transition State Theory and ab initio calculations Veerabhadrarao Kaliginedi, Mohamad Akbar Ali and B.Rajakumar. International Journal of Quantum Chemistry 111 (2011), DOI: 10.1002/qua.23075
  5. Computational studies on CHF2CHFCHF2 (HFC-245ea) + OH reaction between 200 and 400 K: Gaussian-3 and transition state theory calculations Mohamad Akbar Ali, B.Rajakumar. International Journal of Chemical Kinetics, 2011, (Accepted)
  6. Thermodynamic and kinetic studies of hydroxyl radical reaction with bromineoxide using density functional theory Mohamad Akbar Ali, B.Rajakumar. Computational and Theoretical Chemistry, 2011, 964, 283.
  7. Kinetic parameters for the reaction of OH radical initiated atmospheric oxidation of (E)-2-pentenal: Ab initio and transition state theory calculations,Upendra, B., Lakshmi Prasanna, D.S., Rajakumar, B.Current Science, Volume 102, Issue 3, February 2012, Pages 460-469.
  8. Rate coefficients and reaction mechanism for the reaction of OH radicals with (E)-CF 3CH=CHF, (Z)-CF 3CH=CHF, (E)-CF3CF=CHF, and (Z)-CF 3CF=CHF between 200 and 400 K: Hybrid density functional theory and canonical variational transition state theory calculations.; Balaganesh,M.,Rajakumar, B.; Journal of Physical Chemistry A, Volume 116, Issue 40, 11 October 2012, Pages 9835-9842.
  9. Theoretical investigations on the kinetics of H-abstraction reactions from CF3CH(OH)CF3 by OH radicals. Srinivasulu, G., Rajakumar, B.; Journal of Physical Chemistry A, Volume 117, Issue 22, 2013, Pages 4534-4544.
  10. Experimental and theoretical rate coefficients for the gas phase reaction of beta-Pinene with OH radical.; Dash, M.R., Rajakumar, B; Atmospheric Environment, Volume 79, November 2013, Pages 161-171.
  11. Thermal decomposition of 1-chloropropane behind the reflected shock waves in the temperature range of 1015-1220 K: Single pulse shock tube and computational studies. Sudhakar, G., Rajakumar, B.; Journal of Chemical Sciences, Volume 126, Issue 4, July 2014, Pages 897-909
  12. Mechanism, kinetics and atmospheric fate of CF3CHCH2, CF3CFCH2, and CF3CFCF2 by its reaction with OH-radicals: CVT/SCT/ISPE and hybrid meta-DFT methods. Balaganesh,M., Rajakumar, B.; Journal of Molecular Graphics and Modelling, Volume 48, March 2014, Pages 60-69.
  13. Experimental and computational investigation on the gas phase reaction of p-cymene with Cl atoms; Dash, M.R., Srinivasulu, G., Rajakumar, B.; Journal of Physical Chemistry A, Volume 119, Issue 4, 29 January 2015, Pages 559-570.
  14. Theoretical investigations of the gas phase reaction of limonene (C10H16) with OH radical; Dash,M.R., Rajakumar,B.; Molecular Physics, 1 February 2015, 14p.
  15. Abstraction and addition kinetics of C2H radicals with CH4, C2H6, C3H8, C2H4, and C3H6: CVT/SCT/ISPE and hybrid meta-DFT methods; Dash, M.R., Rajakumar, B.; Physical Chemistry Chemical Physics, Volume 17, Issue 5, 7 February 2015, Pages 3142-3156.
  16. Experimental and computational investigation on the gas phase reaction of ethyl formate with Cl atoms.; Balaganesh, M., Dash, M.R., Rajakumar, B.; Journal of Physical chemistry A , Volume 118, Issue 28, 17 July 2014, Pages 5272-5278.
  17. Theoretical investigations on the kinetics of p-cymene + OH reaction. Dash, M.R., Rajakumar, B.; Chemical Physics Letters, Volume 597, 28 March 2014, Pages 75-85.
  18. Gas Phase Kinetics of 2, 2, 2-trifluoroethylbutyrate with Cl Atom: An Experimental and Theoretical Study. Srinivasulu Gonu and Balla Rajakumar, J.Phys.Chem.A 2015, 119, 9294-9306
  19. Experimental and theoretical study on thermal decomposition of methyl butanoate behind reflected shock waves; A. Parandaman, M. Balaganesh and B. Rajakumar; RSC Adv., 2015, 5, 86536-86550.
  20. Reaction kinetics of Cl atoms with limonene: An experimental and theoretics study. Manas Ranja Dash, B. Rajakumar. Atmos. Environ. 2104, 99, 18
  21. Rate coefficients for the gas-phase reaction of OH radical with alpha-pinene: An experimental and computational study. Dash, M.R., Balaganesh,M., Rajakumar, B.; Molecular Physics, Volume 112, Issue 11, 3 June 2014, Pages 1495-1511.
  22. Addition and abstraction kinetics of H atom with propylene and isobutylene between 200 and 2500 K: A DFT study, A. Parandaman and B. Rajakumar, Chemical Physics, 491(2017), 82-94.
  23. Thermal Decomposition of 2-Pentanol: A Shock Tube Study and RRKM Calculations Parandaman Arathala, and Balla Rajakumar,J. Phys. Chem. A, DOI: 10.1021/acs.jpca.6b06386.
  24. Kinetics of the thermal decomposition of tetramethylsilane behind the reflected shock waves between 1058 and 1194 K, A. PARANDAMAN and B. RAJAKUMAR, J. Chem. Sci., 2016, 128, 573-588.
  25. Rate coefficients for hydrogen abstraction reaction of pinonaldehyde (C10H16O2) with Cl atoms between 200 and 400 K: A DFT study, G SRINIVASULU and B RAJAKUMAR, J. Chem. Sci., 2016, 128, 977-989.
  26. Is H Atom Abstraction Important in the Reaction of Cl with 1-Alkenes? M. P. Walavalkar, S. Vijayakumar, A. Sharma, B. Rajakumar and S. Dhanya, J.Phys.Chem.A, 2016, 120, 4096-4107.
  27. Measuring Temperature of Reflected Shock Wave Using a Standard Chemical Reaction, M. Kiran Singh, B. Rajakumar and E. Arunan, Journal of the Indian Institute of Science, 2016, 96,1.
  28. Kinetic investigations on the chlorine atom sensitized photo-oxidization reactions with a series of 1-alkenes in troposphere.” S. Vijayakumar and B. Rajakumar, Environ. Sci. Pollut. Res. 2018, 25, 4387-4405.
  29. Experimental and computational kinetic investigations for the reactions of Cl atoms with unsaturated ketones in gas phase. S. Vijayakumar, Avinash Kumar and B. Rajakumar. New J. Chem., 2017,41, 14299-14314.
  30. Experimental and RRKM investigations on the degradation of ethyl formate”, B. Rajakumar, M. Balaganseh and A. Parandaman, ChemistrySelect 2017, 2, 11603 – 11614.
  31. Shock tube study and RRKM calculations on thermal decomposition of 2-chloroethyl methyl ether, A. Parandaman and B. Rajakumar, Combustion and Flame, 186 (2017), 263-276.
  32. An Experimental and Computational Study on the Cl Atom Initiated Photo-Oxidization Reactions of Butenes in the Gas Phase, S.Vijayakumar and B.Rajakumar, J. Phys. Chem. A, 2017, 121, 5487–5499
  33. Kinetic investigations of Cl atoms initiated photo oxidation reactions of cyclic unsaturated hydrocarbons in the gas phase: an experimental and theoretical study, S.Vijayakumar, C.B Ramya, Avinash Kumar and B.Rajakumar, N. J. Chem. 2017, 41, 7491 – 7505.
  34. Kinetic investigations of chlorine atom initiated photo oxidation reactions of 2,3-dimethyl-1,3- butadiene in the gas phase: an experimental and theoretical study, S. Vijayakumar and B. Rajakumar, RSC Adv., 2016, 6, 67739.
  35. Experimental and theoretical investigations on the reaction of 1,3-butadiene with Cl atom in the gas phase, S.Vijayakumar and B.Rajakumar, J. Phys. Chem. A. 2017, 121, 1976−1984.
  36. Cl initiated photo oxidation reactions of methyl propionate in atmospheric condition” C. B. Ramya and B. Rajakumar. Env. Sci. Poll. Res. 2018. (Accepted).
  37. Kinetic investigations on the gas phase reaction of 2,2,2-trifluoroethylbutyrate with OH radicals: An experimental and theoretical study. G. Srinivasulu, S. Vijayakumar and B. Rajakumar Chem. Sel. 2018. (Accepted).
  1. [1] Unimolecular HCl elimination from 1,2-dichloroethane: A Single Pulse Shock Tube and ab initio study. B.Rajakumar, K. P. J. Reddy, E. Arunan. J. Phys. Chem. A 2002, 106, 8366.
  2. Chemical kinetics studies at high temperature using Shock Tubes. B.Rajakumar, D. Anandraj, K. P. J. Reddy and E. Arunan. J. Ind. Inst. Sci. 2002, 82, 37.
  3. Ab initio, DFT and transition state theory calculations on 1, 2-HF, HCI and CIF elimination reactions from CH2FCH2Cl. B.Rajakumar, E. Arunan. Phys. Chem. Chem. Phys. 2003, 5, 3897-3904.
  4. Thermal decomposition of 2-fluoroethanol: A Shock Tube and ab initio study. B.Rajakumar, K. P. J. Reddy, E. Arunan. J. Phys. Chem. A. 2003, 107, 9782- 9793.
  5. Rate Coefficients for the Reaction of hydroxyl radical with FCH2CH2OH between 250 and 355K. B. Rajakumar, Robert W. Portmann, James B. Burkholder, A. R. Ravishankara. Phys. Chem. Chem. Phys. 2005, 7, 2498-2505.
  6. Kinetics of Quenching of OH (v=1) and OD (v=1) by H2O and D2O from 260 to 370K. David C. McCabe, B.Rajakumar, P. Marshall, I. W. M. Smith, A. R. Ravishankara. Phys. Chem. Chem. Phys. 2006, 8, 4563.
  7. Rate coefficients for the relaxation of OH(v=1) by O2at Temperatures from 204-371 K and by NO2 from 243-372 K. David C. McCabe, B.Rajakumar, I. W. M. Smith, A. R. Ravishankara. Chem. Phys. Lett. 2006, 421, 111-117.
  8. Kinetics of the reaction of OH radical with CF3CH2CH3, CHF2CHFCHF2 and CF3CHFCHF2 in the temperature range of 238-375K. B. Rajakumar, R. W. Portmann, James B. Burkholder, A. R. Ravishankara. J. Phys. Chem. A. 2006, 110, 6724.
  9. Visible absorption spectrum of acetyl radical. B. Rajakumar, Thomas Gericzak, John E. Flad, A. R. Ravishankara, James B. Burkholder, J. Phys. Chem. A. 2007, 111, 8950-8958. (Cover page Article, issue 37).
  10. The CH3CHO quantum yield in the 248 nm photolysis of acetone, methyl ethyl ketone, and biacetyl . B.Rajakumar, Thomasz Gierczak, John E. Flad, A. R. Ravishankara, James B. Burkholder. J. Photo. Chem. Photo. Biol. A: Chemistry, 2008, 199, 336-344.
  11. Rate coefficients for the reactions of the acetyl radical, CH3CO, with Cl2 between 253 and 384K . Thomasz Gierczak, B.Rajakumar, John E. Flad, James B. Burkholder. Int. J. Chem. Kinet. 2009, 41, 543-553. Year of Publication : 2009.
  12. ISSW 30. Year of Publication : 2010.
  13. Kinetics of OH radical reaction with CH3CHFCH2F (HFC-245eb) between 200 and 400K: G3MP2, G3B3 and Transition State Theory Calculations. Calculations Mohamad Akbar Ali, B.Rajakumar. Journal of Molecular Structure: THEOCHEM, 2010, 949, 73.
  14. Rate Coefficients for the Reactions of OH with n-propanol and iso-propanol between 235 and 376K . B.Rajakumar, David C. McCabe, Ranajit K. Talukdar, A. R. Ravishankara, Int. J. Chem. Kinet. 2010, 43, 10.
  15. Kinetic study of the reaction of the acetyl radical, CH3CO, with O3 using cavity ring-down spectroscopy. Thomasz Gierczak, B.Rajakumar, John E. Flad, James B. Burkholder. Chem. Phys. Lett. 2010, 484, 160-164.
  16. Rate coefficients for the Reaction of OH with CF3CH2CH3 (HFC-263fb) between 200 and 400K: ab initio, DFT and Transitions State Theory Calculations. Mohamad Akbar Ali, B. Rajakumar. J. Comp. Chem. 2010, 31, 500-509.
  17. Kinetic parameters of abstraction reactions of OH radical with ethylene, fluoroethylene, cis- and trans-1,2-difluoroethylene and 1,1-difluoroethylene, in the temperature range of 200-400 K: Gaussian-3/B3LYP theory. Ali, M.A., Upendra, B., Rajakumar, B.Chemical Physics Letters, Volume 511, Issue 4-6, 5 August 2011, Pages 440-446.
  18. Abstraction Kinetics of H-Atom by OH Radical from Pinonaldehyde: Ab Initio and Transition-State Theory Calculations. Manas Ranjan Dash and B. Rajakumar; J. Phys. Chem. A, 2012, 116, 5856-5866.
  19. Kinetic parameters of OH radical reaction with CH3OCH2F (HFE-161) in the temperature range of 200 400 K: Transition State Theory and ab initio calculations . Veerabhadrarao Kaliginedi, Mohamad Akbar Ali and B.Rajakumar. International Journal of Quantum Chemistry 111 (2011), DOI: 10.1002/qua.23075.
  20. Computational studies on CHF2CHFCHF2 (HFC-245ea) + OH reaction between 200 and 400 K: Gaussian-3 and transition state theory calculations . Mohamad Akbar Ali, B.Rajakumar. International Journal of Chemical Kinetics, 2011, (Accepted)
  21. Thermodynamic and kinetic studies of hydroxyl radical reaction with bromineoxide using density functional theory . Mohamad Akbar Ali, B.Rajakumar. Computational and Theoretical Chemistry, 2011, 964, 283.
  22. Kinetic parameters for the reaction of OH radical initiated atmospheric oxidation of (E)-2-pentenal: Ab initio and transition state theory calculations . Upendra, B., Lakshmi Prasanna, D.S., Rajakumar, B.Current Science, Volume 102, Issue 3, February 2012, Pages 460-469.
  23. Rate coefficients and reaction mechanism for the reaction of OH radicals with (E)-CF 3CH=CHF, (Z)-CF 3CH=CHF, (E)-CF3CF=CHF, and (Z)-CF 3CF=CHF between 200 and 400 K: Hybrid density functional theory and canonical variational transition state theory calculations. Balaganesh,M.,Rajakumar, B.; Journal of Physical Chemistry A, Volume 116, Issue 40, 11 October 2012, Pages 9835-9842.
  24. Theoretical investigations on the kinetics of H-abstraction reactions from CF3CH(OH)CF3 by OH radicals. . Srinivasulu, G., Rajakumar, B.; Journal of Physical Chemistry A, Volume 117, Issue 22, 2013, Pages 4534-4544.
  25. Experimental and theoretical rate coefficients for the gas phase reaction of beta-Pinene with OH radical. Dash, M.R., Rajakumar, B; Atmospheric Environment, Volume 79, November 2013, Pages 161-171.
  26. Rate coefficients for the gas-phase reaction of OH radical with alpha-pinene: An experimental and computational study. Dash, M.R., Balaganesh,M., Rajakumar, B.; Molecular Physics, Volume 112, Issue 11, 3 June 2014, Pages 1495-1511.
  27. Reaction kinetics of Cl atoms with limonene: An experimental and theoretics study. Manas Ranja Dash, B. Rajakumar. Atmos. Environ. 2104, 99, 183.
  28. Experimental and theoretical study on thermal decomposition of methyl butanoate behind reflected shock waves. A. Parandaman, M. Balaganesh and B. Rajakumar; RSC Adv., 2015, 5, 86536-86550.
  29. Gas Phase Kinetics of 2, 2, 2-trifluoroethylbutyrate with Cl Atom: An Experimental and Theoretical Study. Srinivasulu Gonu and Balla Rajakumar, J.Phys.Chem.A 2015, 119, 9294-9306.
  30. Thermal decomposition of 1-chloropropane behind the reflected shock waves in the temperature range of 1015-1220 K: Single pulse shock tube and computational studies. Sudhakar, G., Rajakumar, B.; Journal of Chemical Sciences, Volume 126, Issue 4, July 2014, Pages 897-909.
  31. Mechanism, kinetics and atmospheric fate of CF3CHCH2, CF3CFCH2, and CF3CFCF2 by its reaction with OH-radicals: CVT/SCT/ISPE and hybrid meta-DFT methods. Balaganesh,M., Rajakumar, B.; Journal of Molecular Graphics and Modelling, Volume 48, March 2014, Pages 60-69.
  32. Theoretical investigations on the kinetics of p-cymene + OH reaction. Dash, M.R., Rajakumar, B.; Chemical Physics Letters, Volume 597, 28 March 2014, Pages 75-85.
  33. Experimental and computational investigation on the gas phase reaction of ethyl formate with Cl atoms. Balaganesh, M., Dash, M.R., Rajakumar, B.; Journal of Physical chemistry A , Volume 118, Issue 28, 17 July 2014, Pages 5272-5278.
  34. Experimental and computational investigation on the gas phase reaction of p-cymene with Cl atoms. Dash, M.R., Srinivasulu, G., Rajakumar, B.; Journal of Physical Chemistry A, Volume 119, Issue 4, 29 January 2015, Pages 559-570.
  35. Theoretical investigations of the gas phase reaction of limonene (C10H16) with OH radical. Dash,M.R., Rajakumar,B.; Molecular Physics, 1 February 2015, 14p.
  36. Abstraction and addition kinetics of C2H radicals with CH4, C2H6, C3H8, C2H4, and C3H6: CVT/SCT/ISPE and hybrid meta-DFT methods. Dash, M.R., Rajakumar, B.; Physical Chemistry Chemical Physics, Volume 17, Issue 5, 7 February 2015, Pages 3142-3156.
  37. Kinetic investigations of chlorine atom initiated photo oxidation reactions of 2,3-dimethyl-1,3- butadiene in the gas phase: an experimental and theoretical study. S. Vijayakumar and B. Rajakumar, RSC Adv., 2016, 6, 67739. Year of Publication : 2016.
  38. Thermal Decomposition of 2-Pentanol: A Shock Tube Study and RRKM Calculations. Parandaman Arathala, and Balla Rajakumar,J. Phys. Chem. A, DOI: 10.1021/acs.jpca.6b06386.
  39. Kinetics of the thermal decomposition of tetramethylsilane behind the reflected shock waves between 1058 and 1194 K. A. PARANDAMAN and B. RAJAKUMAR, J. Chem. Sci., 2016, 128, 573-588.
  40. Rate coefficients for hydrogen abstraction reaction of pinonaldehyde (C10H16O2) with Cl atoms between 200 and 400 K: A DFT study. G SRINIVASULU and B RAJAKUMAR, J. Chem. Sci., 2016, 128, 977-989.
  41. Is H Atom Abstraction Important in the Reaction of Cl with 1-Alkenes? M. P. Walavalkar, S. Vijayakumar, A. Sharma, B. Rajakumar and S. Dhanya, J.Phys.Chem.A, 2016, 120, 4096-4107.
  42. Measuring Temperature of Reflected Shock Wave Using a Standard Chemical Reaction. M. Kiran Singh, B. Rajakumar and E. Arunan, Journal of the Indian Institute of Science, 2016, 96,1.
  43. Kinetic investigations on the chlorine atom sensitized photo-oxidization reactions with a series of 1-alkenes in troposphere. S. Vijayakumar and B. Rajakumar, Environ. Sci. Pollut. Res. 2018, 25, 4387-4405.
  44. Experimental and computational kinetic investigations for the reactions of Cl atoms with unsaturated ketones in gas phase. S. Vijayakumar, Avinash Kumar and B. Rajakumar. New J. Chem., 2017,41, 14299-14314.
  45. Experimental and RRKM investigations on the degradation of ethyl formate. B. Rajakumar, M. Balaganseh and A. Parandaman, ChemistrySelect 2017, 2, 11603 – 11614.
  46. Shock tube study and RRKM calculations on thermal decomposition of 2-chloroethyl methyl ether. A. Parandaman and B. Rajakumar, Combustion and Flame, 186 (2017), 263-276.
  47. An Experimental and Computational Study on the Cl Atom Initiated Photo-Oxidization Reactions of Butenes in the Gas Phase. S.Vijayakumar and B.Rajakumar, J. Phys. Chem. A, 2017, 121, 5487–5499.
  48. Kinetic investigations of Cl atoms initiated photo oxidation reactions of cyclic unsaturated hydrocarbons in the gas phase: an experimental and theoretical study. S.Vijayakumar, C.B Ramya, Avinash Kumar and B.Rajakumar, N. J. Chem. 2017, 41, 7491 – 7505.
  49. Addition and abstraction kinetics of H atom with propylene and isobutylene between 200 and 2500 K: A DFT study. A. Parandaman and B. Rajakumar, Chemical Physics, 491(2017), 82-94.
  50. Experimental and theoretical investigations on the reaction of 1,3-butadiene with Cl atom in the gas phase. S.Vijayakumar and B.Rajakumar, J. Phys. Chem. A. 2017, 121, 1976−1984.
  51. Cl initiated photo oxidation reactions of methyl propionate in atmospheric condition. C. B. Ramya and B. Rajakumar. Env. Sci. Poll. Res. 2018. (Accepted).
  52. Kinetic investigations on the gas phase reaction of 2,2,2-trifluoroethylbutyrate with OH radicals: An experimental and theoretical study. ; G. Srinivasulu, S. Vijayakumar and B. Rajakumar Chem. Sel. 2018. (Accepted).