DEPARTMENT OF CHEMISTRY
INDIAN INSTITUTE OF TECHNOLOGY MADRAS

CY7430 : Ion Chemistry

Physical Chemistry
  • Mass spectrometry in 90’s and beyond, mass spectrometer as laboratory-tandem mass spectrometers-MS/MS with electric, magnetic, quadrupole, time of flight, FT- ICR and ion traps-hybrid instruments.
  • Collisional activation and reaction-kinematics-dynamics-collision energy and target gas effects-MS/MS in ion structures-reaction mechanism – thermochemistry.
  • Analytical applications-attomole chemistry. SIMS and analysis of surfaces.
  • Ion/molecule scattering-surface induced dissociation and reaction surface transformation ultrathin films.
  • Ion chromatography-state selction in MS/MS spectrometry neutralization reionization mass spectrometry.
  • Laser vapourization-cluster chemistry with mass spectrometers-clusters- fullerenes metallocarbohedrenes-modern tools and novel applications. Ion scattering methods – ISS and RBS.

References:

  1. J.H. Futrell, Gaseous Ion Chemistry and Mass Spectrometry”, Wiley, New York 1986.
  2. F.W.McLafferty, Ed., “Tandem Mass Spectrometry” Wiley, New York, 1983.
  3. M.T.Bowers, “sGas Phase Ion Chemistry”, Academic Pres, New York, 1979.
  4. D.H.Russel, Ed., “Gas Phase Inorganic Chemistry”, Plenum Press New York, 1989.
  5. Busch, G.L.Glish and S.A.McLuckey, “Mass Spectrometry/Mass Spectrometry, Chemical Applications of Tandem Mass Spectrometry VCH , New York, 1988.
  6. Recent reviews such as, S.J.Pachuta and R.G.Cooks, Chem. Rev., 87 (1987) 674.R.G.Cooks, T.Ast, T.Pradeep and V.H.Wysocki, Acc. Chem.Res.’27 (1994) 316. D.K.Bohme, Chem.Rev., 92 (1992) 1487.
  7. K.Eller and H.Schwarz, Chem. Rev., 91 (1991) 1121.
  8. Recent papers inthe area; journals covered are, J.Phys. Chem., J.Chem. Phys., J.Am.Chem.Soc., Int.J.Mass Spectrom. Ion Processes, Acc. Chem. Res., Chem. Rev., Ann. Rev. Phys. Chem., J. Mass Spectrom.